TiCl₃(4-t-BuC₆H₄CHPPh₂=NC₆H₂Me₃-2,4,6)

Base Information

• Chemical Name: TiCl₃(4-t-BuC₆H₄CHPPh₂=NC₆H₂Me₃-2,4,6)
• CAS No.: 388123-80-6
• Molecular Formula: C₃₂H₃₅Cl₃NPTi
• Molecular Weight: 618.849
• Mol file: 388123-80-6.mol

Synonyms:

Chemical Property of TiCl₃(4-t-BuC₆H₄CHPPh₂=NC₆H₂Me₃-2,4,6)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of TiCl₃(4-t-BuC₆H₄CHPPh₂=NC₆H₂Me₃-2,4,6)

There total 4 articles about TiCl₃(4-t-BuC₆H₄CHPPh₂=NC₆H₂Me₃-2,4,6) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

titanium tetrachloride (7550-45-0) + 4-t-BuC6H4CH2PPh2=NC6H2Me3-2,4,6 (388123-78-2) → TiCl3(4-t-BuC6H4CHPPh2=NC6H2Me3-2,4,6) (388123-80-6)

Guidance literature:

With n-BuLi; In toluene; byproducts: [4-t-BuC6H4CH2PPh2NHC6H2Me3-2,4,6]Cl; under N2, Schlenk techniques; 1 equiv. of n-BuLi added dropwise to soln.of ligand in toluene at ambient temp.; stirred for 2 h; soln. of TiCl4 (1 equiv.) in toluene added dropwise at -78°C; warmed to room tem p.; stirred for 12 h; filtered; concd.; light petroleum added; elem. anal.;

DOI:10.1039/b105038a

Reference yield:

4-t-BuC6H4CH2PPh2=NC6H2Me3-2,4,6 (388123-78-2) → TiCl3(4-t-BuC6H4CHPPh2=NC6H2Me3-2,4,6) (388123-80-6)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: ⁽²⁾H₈-toluene

In ⁽²⁾H₈-toluene; toluene;

DOI:10.1039/b105038a

Reference yield:

TiCl4(4-t-BuC6H4CH2PPh2=NC6H2Me3-2,4,6) (388123-79-3) → TiCl3(4-t-BuC6H4CHPPh2=NC6H2Me3-2,4,6) (388123-80-6)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: HCl; under N2, Schlenk techniques; soln. of Ti complex in toluene-d8 heated to 30°C; not isolated; detd. by (31)P NMR spectroscopy;

DOI:10.1039/b105038a

upstream raw materials:

titanium tetrachloride

4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6

TiCl₄(4-t-BuC₆H₄CH₂PPh₂=NC₆H₂Me₃-2,4,6)

triethylamine