trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II)

Base Information

Chemical Name:trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II)
CAS No.:126790-13-4
Molecular Formula:C₃₄H₃₈Cl₂O₄P₂Ru
Molecular Weight:744.597
Hs Code.:

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Chemical Property of trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II)

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Technology Process of trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II)

There total 2 articles about trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 15529-49-4,41756-81-4
dichlorotris(triphenylphosphine)ruthenium(II)

: 110428-32-5
2-diphenylphosphinomethyl-1,4-dioxane

: 126790-16-7
2Cl^(1-)*Ru⁽²⁺⁾*2(C₆H₅)2PCH₂C₄H₇O₂=(ClRu((C₆H₅)2PCH₂C₄H₇O₂)2)Cl

: 126790-13-4
trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II)

Guidance literature:: In dichloromethane; addn. of phosphane ligand to Ru-complex in CH2Cl2, heating to boiling (ca. 10 min), react. under Ar or N2; evapn. (vac.), pptn. by addn. of ether, filtration, washing with ether, drying in vac.; elem. anal.;

Reference yield: 16.0%

: 126790-15-6
cis-dicarbonyl-cis-dichloro-trans-bis{(1,4-dioxanylmethyl)diphenylphosphane-P}ruthenium(II)

: 126790-13-4
trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II)

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); irradn. of Ru-complex in THF for 1 h at 40°C while passing Ar through the soln.; evapn. (vac.), recrystn. from C2H5OH; elem. anal.;

Reference yield: 84.0%

: 126790-13-4
trans-dichloro-cis-bis{(1,4-dioxanylmethyl)diphenylphosphane-O,P}ruthenium(II)

: 126790-15-6
cis-dicarbonyl-cis-dichloro-trans-bis{(1,4-dioxanylmethyl)diphenylphosphane-P}ruthenium(II)

Guidance literature:: With carbon monoxide; In toluene; heating of Ru-complex in toluene at reflux for 4 h (under CO) to 110°C; pptn. by addn. of n-hexane, filtration, drying in vac. at room temp.; elem. anal.;