Technology Process of Rh2(O2CCH3)3{(C6H4)P(C6H5)2}(P(C6H5)3)(H2O)
There total 2 articles about Rh2(O2CCH3)3{(C6H4)P(C6H5)2}(P(C6H5)3)(H2O) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triphenylphosphine;
In
chloroform;
Irradiation (UV/VIS); solid mixt. of Rh compd. and phosphine dissolved in CHCl3, irradiated with Hg-vapour lamp for 50 min; solvent removed, redissolved in CH2Cl2-hexane, chromy. (silica gel, CH2Cl2-hexane, CH2Cl2-hexane-Me2CO) green band collected, evapn., residue dissolved in CH2Cl2, addn. of hexane; elem. anal.;
DOI:10.1039/DT9940000545
- Guidance literature:
-
With
P(C6H5)3;
In
toluene;
under Ar, molar educt ratio Rh-compd.:PPh3 = 1:2, refluxed for 1 h; evapn. to dryness, column chromy. (silica gel/acetone-hexane 1:4), first band: (H2O)2-compd., second band: concn. under vac., dissolved in CH2Cl2/acetic acid, addn. of hexane, (PPh3)(HO2CCH3)-compd., concn., addn. of hexane: (PPh3)(H2O)-compd.;
- Guidance literature:
-
With
acetic acid;
In
dichloromethane;
addn. of acetic acid to soln. of Rh compd. in CH2Cl2; concn.; elem. anal.;
DOI:10.1039/DT9940000545
