(-)-phenyl perdeuteriophenyl sulfoxide

Base Information

• Chemical Name: (-)-phenyl perdeuteriophenyl sulfoxide
• CAS No.: 1017265-34-7
• Molecular Formula: C₁₂H₁₀OS
• Molecular Weight: 207.237
• Mol file: 1017265-34-7.mol

Synonyms:

Chemical Property of (-)-phenyl perdeuteriophenyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (-)-phenyl perdeuteriophenyl sulfoxide

There total 2 articles about (-)-phenyl perdeuteriophenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bromobenzene-d5 (4165-57-5) + benzyl phenyl sulfoxide (7417-81-4,20246-02-0,73610-10-3,210539-77-8,833-82-9) → (-)-phenyl perdeuteriophenyl sulfoxide (1017265-34-7)

Guidance literature:

With (2R)-1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; at 50 ℃; for 24h; enantioselective reaction; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.7b03623

Reference yield:

phenylmagnesium bromide-d5 (84783-81-3) + O-(1S,2R,5S)-(+)-menthyl (R)-benzenesulfinate (1017265-32-5) → (-)-phenyl perdeuteriophenyl sulfoxide (1017265-34-7)

Guidance literature:

In diethyl ether; at 20 ℃; for 3h;

DOI:10.1016/j.tetasy.2007.12.014

upstream raw materials:

phenylmagnesium bromide-d5

O-(1S,2R,5S)-(+)-menthyl (R)-benzenesulfinate

bromobenzene-d5

benzyl phenyl sulfoxide