{Ir(carbon monoxide)(3,6-bis-(3,5-dimethylpyrazol-1-yl)-pyridazine)(triphenylphosphine)2}ClO₄

Base Information

• Chemical Name: {Ir(carbon monoxide)(3,6-bis-(3,5-dimethylpyrazol-1-yl)-pyridazine)(triphenylphosphine)2}ClO₄
• CAS No.: 90442-55-0
• Molecular Formula: C₅₁H₄₆IrN₆OP₂*ClO₄
• Molecular Weight: 1112.58
• Mol file: 90442-55-0.mol

Synonyms:

Chemical Property of {Ir(carbon monoxide)(3,6-bis-(3,5-dimethylpyrazol-1-yl)-pyridazine)(triphenylphosphine)2}ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Ir(carbon monoxide)(3,6-bis-(3,5-dimethylpyrazol-1-yl)-pyridazine)(triphenylphosphine)2}ClO₄

There total 1 articles about {Ir(carbon monoxide)(3,6-bis-(3,5-dimethylpyrazol-1-yl)-pyridazine)(triphenylphosphine)2}ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

bis(triphenylphosphine)iridium(I) carbonyl chloride (15318-31-7,14871-41-1,59246-46-7) + silver perchlorate + 3,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine (29334-74-5) → {Ir(carbon monoxide)(3,6-bis-(3,5-dimethylpyrazol-1-yl)-pyridazine)(triphenylphosphine)2}ClO4 (90442-55-0)

Guidance literature:

In acetone; byproducts: AgCl; suspn. of Ir complex in acetone stirred, under N2, for 30 min with AgClO4, AgCl filtered off, filtrate added to acetone soln. of amine ligand, stirred for 15 min; concd. in vac., pptd. with ether, filtered off, washed with ether, air-dried, elem. anal.;

DOI:10.1016/S0277-5387(00)88052-3

upstream raw materials:

bis(triphenylphosphine)iridium(I) carbonyl chloride

3,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine