2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid

Base Information

• Chemical Name: 2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid
• CAS No.: 1265529-85-8
• Molecular Formula: C₁₄H₁₈O₈
• Molecular Weight: 314.292
• Mol file: 1265529-85-8.mol

Synonyms:

Chemical Property of 2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid

There total 1 articles about 2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethyl 2,5-(dihydroxy)terephthalate (5870-38-2) + 2-Bromoethyl methyl ether (6482-24-2) → 2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid (1265529-85-8)

Guidance literature:

diethyl 2,5-(dihydroxy)terephthalate; 2-Bromoethyl methyl ether; With potassium carbonate; In acetonitrile; for 24h; Reflux;

With sodium hydroxide; In ethanol; water; at 50 ℃; for 24h;

In ethanol; water; pH=1;

DOI:10.1039/c8cy01493k

Reference yield:

tetrakis(trifluoroacetato)rhodium(II) + 2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid (1265529-85-8) → 2C14H16O8(2-)*2Rh(2+)

Guidance literature:

With potassium carbonate; In ethyl acetate; for 48h;

DOI:10.1039/c8cy01493k

Reference yield:

1,4-diaza-bicyclo[2.2.2]octane (280-57-9,88935-43-7) + zinc(II) nitrate hexahydrate + 2,5-bis(2-methoxyethoxy)-1,4-benzene dicarboxylic acid (1265529-85-8) → Zn2(2,5-bis(methoxyethoxy)-1,4-benzenedicarboxylate)2(1,4-diazabicyclo[2.2.2]octane)

Guidance literature:

In N,N-dimethyl-formamide; at 120 ℃; for 24h;

DOI:10.1039/c6ta03266d

upstream raw materials:

diethyl 2,5-(dihydroxy)terephthalate

2-Bromoethyl methyl ether

Refernces