1,2-Benzenedicarboxylic acid, mono(2-phenylethyl) ester

Base Information

• Chemical Name: 1,2-Benzenedicarboxylic acid, mono(2-phenylethyl) ester
• CAS No.: 105578-59-4
• Molecular Formula: C16H14O4
• Molecular Weight: 270.285
• Mol file: 105578-59-4.mol

Synonyms:

Chemical Property of 1,2-Benzenedicarboxylic acid, mono(2-phenylethyl) ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Benzenedicarboxylic acid, mono(2-phenylethyl) ester

There total 3 articles about 1,2-Benzenedicarboxylic acid, mono(2-phenylethyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

phthalic anhydride (85-44-9) + 2-phenylethanol (60-12-8) → 2-phenylethyl hydrogen benzene-1,2-dicarboxylate (105578-59-4)

Guidance literature:

With iron(III)-acetylacetonate; sodium carbonate; In n-heptane; at 105 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.tet.2011.01.009

Reference yield: 92.0%

phthalic anhydride (85-44-9) + 2-phenylethanol (60-12-8) → 2-phenylethyl hydrogen benzene-1,2-dicarboxylate (105578-59-4) + phthalic acid diphenethyl ester (13330-42-2)

Guidance literature:

phthalic anhydride; With molybdenium(VI) dioxodichloride; In dichloromethane; at 20 ℃; for 1h;

2-phenylethanol; In dichloromethane; at 10 ℃; for 78h;

DOI:10.1021/jo048363v

Reference yield:

phthalic anhydride (85-44-9) → 2-phenylethyl hydrogen benzene-1,2-dicarboxylate (105578-59-4)

Guidance literature:

With diethyl ether;

upstream raw materials:

phthalic anhydride

2-phenylethanol

Refernces

• 1、 Weng, Shiue-Shien,Ke, Chih-Shueh,Chen, Fong-Kuang,Lyu, You-Fu,Lin, Guan-Ying. "Transesterification catalyzed by iron(III) β-diketonate species". experimental part. p. 1640 - 1648. Retrieved 2011/04/17.
• 2、 De Saint Laumer, Jean-Yves,Frerot, Eric,Herrmann, Andreas. "Controlled release of perfumery alcohols by neighboring-group participation. Comparison of the rate constants for the alkaline hydrolysis of 2-acyl-, 2-(hydroxymethyl)-, and 2-carbamoylbenzoates". . p. 2871 - 2899. Retrieved 2007/10/03.