iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

Base Information

Chemical Name:iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)
CAS No.:1203584-61-5
Molecular Formula:C₄₀H₅₁N₃O₁₉
Molecular Weight:877.854
Hs Code.:

iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

Synonyms:

Suppliers and Price of iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

There total 5 articles about iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1203584-60-4
iso-propyl (methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

: 1203584-70-6
3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

: iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

: 1203584-61-5
iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -20 - 5 ℃; for 1h; optical yield given as %de; Molecular sieve; Inert atmosphere;
DOI:10.1080/07328300903105108

Reference yield:

: 1203584-68-2
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

: iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

: 1203584-61-5
iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

Guidance literature:: Multi-step reaction with 3 steps

1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere

2: caesium carbonate / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere

3: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / -20 - 5 °C / Molecular sieve; Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; caesium carbonate; acetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1080/07328300903105108

Reference yield:

: 1082706-19-1
C₁₈H₂₁N₃O₁₂

: iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

: 1203584-61-5
iso-propyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranosyl-(1->4)-(methyl 3-O-benzyl-2-O-pivaloyl-α-L-idopyranosyluronate)

Guidance literature:: Multi-step reaction with 2 steps

1: caesium carbonate / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere

2: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / -20 - 5 °C / Molecular sieve; Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; caesium carbonate; In dichloromethane;
DOI:10.1080/07328300903105108