tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

Base Information

Chemical Name:tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose
CAS No.:1203584-68-2
Molecular Formula:C₃₄H₃₉N₃O₁₂Si
Molecular Weight:709.782
Hs Code.:

Synonyms:tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

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Chemical Property of tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

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Technology Process of tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

There total 4 articles about tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1203584-54-6
1-O-tert-butyldiphenylsilyl-3,4,6-tri-O-acetyl-2-deoxy-2-amino-β-D-glucopyranoside

: 70-34-8,65727-75-5
2,4-Dinitrofluorobenzene

: 1203584-68-2
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

Guidance literature:: With potassium hydrogencarbonate; In tetrahydrofuran; water; at 20 ℃; for 6h; Inert atmosphere;
DOI:10.1080/07328300903105108

Reference yield:

: 114297-26-6
1,3,4,6-tetra-O-acetyl-2-deoxy-2-{[(4-methoxyphenyl)methylidene]amino}-D-glucopyranose

: 1203584-68-2
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 4 steps

1: ammonia / tetrahydrofuran; methanol / 1.5 h / 0 °C

2: 1H-imidazole / dichloromethane / 2 h / 20 °C / Inert atmosphere

3: hydroxylamine hydrochloride / tetrahydrofuran; water / 0.75 h / 20 °C / Inert atmosphere

4: potassium hydrogencarbonate / tetrahydrofuran; water / 6 h / 20 °C / Inert atmosphere

With 1H-imidazole; hydroxylamine hydrochloride; ammonia; potassium hydrogencarbonate; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1080/07328300903105108

Reference yield:

: 1203584-53-5
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

: 1203584-68-2
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: hydroxylamine hydrochloride / tetrahydrofuran; water / 0.75 h / 20 °C / Inert atmosphere

2: potassium hydrogencarbonate / tetrahydrofuran; water / 6 h / 20 °C / Inert atmosphere

With hydroxylamine hydrochloride; potassium hydrogencarbonate; In tetrahydrofuran; water;
DOI:10.1080/07328300903105108