[(η5-C5H4COC6H5)Fe(CO)2CH3]

Base Information

Chemical Name:[(η5-C5H4COC6H5)Fe(CO)2CH3]
CAS No.:476170-16-8
Molecular Formula:C₁₅H₁₂FeO₃
Molecular Weight:296.105
Hs Code.:

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Chemical Property of [(η5-C5H4COC6H5)Fe(CO)2CH3]

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Technology Process of [(η5-C5H4COC6H5)Fe(CO)2CH3]

There total 1 articles about [(η5-C5H4COC6H5)Fe(CO)2CH3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: dicarbonyl(cyclopentadienyl)methyliron(II)

: 98-88-4
benzoyl chloride

: 476170-16-8
[(η5-C5H4COC6H5)Fe(CO)2CH3]

Guidance literature:: With sec.-butyllithium; In tetrahydrofuran; byproducts: LiCl; s-BuLi was added to a THF-soln. of complex at -78°C, transfered to soln. of C6H5COCl in THF cooled to -78°C over 30 min, stirred for 2 h at this temp., allowed to warm to room temp. (N2); passed through silica gel under N2, rinsed with ether, evapd., chromd. on silica gel column (ether-pentane) twice; elem. anal.;
DOI:10.1016/S0022-328X(02)01257-3

Reference yield: 98.0%

: 16940-66-2
sodium tetrahydroborate

: 476170-16-8
[(η5-C5H4COC6H5)Fe(CO)2CH3]

: 476170-17-9,476170-22-6
[(η5-C5H4CH(OH)C6H5)Fe(CO)2CH3]

Guidance literature:: In methanol; NaBH4 was slowly added to the soln. of complex in methanol at 0°C, stirred for 90 min (N2); solvent was removed under reduced pressure, dissolved in ether, extd. with water, dried over Na2SO4, evapd. under reduced pressure, dissolved inethernol, passed through silica gel;
DOI:10.1016/S0022-328X(02)01257-3

Reference yield: 80.0%

: 476170-16-8
[(η5-C5H4COC6H5)Fe(CO)2CH3]

: borane tetrahydrofuran

: [(η5-C5H4COC6H5)Fe(CO)2CH3]

Guidance literature:: With CBS catalyst; In tetrahydrofuran; BH3*THF and complex in THF was added to oxazaborolidine complex (CBS catalyst) in THF at 0°C over 8 min, stirred at 0°C for 105 min (N2); solvent was removed under reduced pressure, dissolved in moist ether anddried over Na2SO4, filtered, the solvent was removed, chromd. on silica gel (pentane-ether);
DOI:10.1016/S0022-328X(02)01257-3