4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine

Base Information

Chemical Name:4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine
CAS No.:86045-66-1
Molecular Formula:C₁₈H₂₃NO₂S
Molecular Weight:317.452
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine

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Technology Process of 4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine

There total 4 articles about 4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 52072-18-1
1,3-dichloro-1-(phenylthio)propane

: 86045-66-1,86045-80-9
4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine

Guidance literature:: Multi-step reaction with 4 steps

1: ZnBr₂ / CH₂Cl₂ / 1.) 0 deg C to room temp., 2.) room temp., 1 h

2: NaI / butan-2-one / 22 h / Heating

3: NH₃ / CHCl₃ / 48 h / Ambient temperature

4: N,N-diethylaniline / toluene / 14 h / Ambient temperature

With ammonia; N,N-diethylaniline; sodium iodide; zinc dibromide; In dichloromethane; chloroform; toluene; butanone;
DOI:10.1021/jo00164a011

Reference yield:

: 86045-65-0,86045-79-6
2-ethyl-2-<3-chloro-1-(phenylthio)propyl>cyclopentanone

: 86045-66-1,86045-80-9
4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine

Guidance literature:: Multi-step reaction with 3 steps

1: NaI / butan-2-one / 22 h / Heating

2: NH₃ / CHCl₃ / 48 h / Ambient temperature

3: N,N-diethylaniline / toluene / 14 h / Ambient temperature

With ammonia; N,N-diethylaniline; sodium iodide; In chloroform; toluene; butanone;
DOI:10.1021/jo00164a011

Reference yield:

: 86045-77-4
2-Ethyl-2-(3-iodo-1-phenylsulfanyl-propyl)-cyclopentanone

: 86045-66-1,86045-80-9
4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine

Guidance literature:: Multi-step reaction with 2 steps

1: NH₃ / CHCl₃ / 48 h / Ambient temperature

2: N,N-diethylaniline / toluene / 14 h / Ambient temperature

With ammonia; N,N-diethylaniline; In chloroform; toluene;
DOI:10.1021/jo00164a011