52072-18-1Relevant academic research and scientific papers
THE COMPATIBILITY OF THE CYANO AND ALKYL CHLORIDE FUNCTIONS IN PHENYLTHIOALKYLATION REACTIONS OF O-SILYLATED ENOLATES
Lee, Thomas V.,Visani, Naina
, p. 5559 - 5560 (2007/10/02)
The compatibility of the cyano group and of chlorides with the conditions of phenylthioalkylation of O-silylated enolates has been demonstrated.
A New Approach for the Total Synthesis of Pentacyclic Aspidosperma Alkaloids. Total Synthesis of dl-16-Methoxytabersonine
Overman, Larry E.,Sworin, Michael,Burk, Robert M.
, p. 2685 - 2690 (2007/10/02)
The pentacyclic Aspidosperma alkaloid dl-16-methoxytabersonine (1) has been synthesized by an efficient convergent sequence.The key step in the synthesis is the "ring-enlarging pyrrolidine annulation" reaction of 7-styrylhydropyridin-7-ols 17 and 18 to gi
