trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II)

Base Information

• Chemical Name: trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II)
• CAS No.: 76125-03-6
• Molecular Formula: C₁₂H₂₄P₂Pt
• Molecular Weight: 425.35
• Mol file: 76125-03-6.mol

Synonyms:

Chemical Property of trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II)

There total 3 articles about trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

sodium tetrahydroborate (16940-66-2) + trans-[PtBr(Ph)(PMe3)2] (192936-51-9) → trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II) (76125-03-6)

Guidance literature:

In ethanol; water; inert atmosphere; in EtOH/water=5:1, excess NaBH4, stirring at room temp. for 3 h; water addn., collection (filtration), recrystn. (Me2CO/MeOH); elem. anal.;

DOI:10.1016/s0020-1693(97)05509-6

Reference yield: 56.0%

sodium tetrahydroborate (16940-66-2) + trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II) (90065-11-5) → trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II) (76125-03-6) + trans-mer-trihydridophenylbis(trimethylphosphine)platinum(IV) (90065-03-5)

Guidance literature:

With silver tetrafluoroborate; In methanol; dichloromethane; under N2, NaBH4 was added to soln. of Pt-complex and AgBF4 (molar ratio1:22) in CH2Cl2-MeOH; evapd. to dryness, extd. with CH2Cl2, filtered, treated with MeOH, concd. in vac., cooled to -50°C, filtered at -78°C, washed with MeOH, dried in vac., recrystd. from ether-n-pentane; elem. anal.;

Reference yield:

[PtCl(Ph)(PMe3)2] (90065-11-5,343573-66-0) → trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II) (76125-03-6)

Guidance literature:

Multi-step reaction with 2 steps

1: AgNO₃ / acetone

2: water; ethanol

With AgNO₃; In ethanol; water; acetone;

DOI:10.1016/s0020-1693(97)05509-6

upstream raw materials:

sodium tetrahydroborate

trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)

trans-[PtBr(Ph)(PMe₃)2]

[PtCl(Ph)(PMe₃)2]

Downstream raw materials:

[(PMe3)2(Ph)Pt(μ-H)Pt(Ph)(PMe3)2][B(C6H5)4]

Refernces

• 1、 Arnold, Dennis P.,Bennett, Martin A.. "Preparation, spectroscopic properties, and reactivity of trans-hydridoaryl and trans-hydridomethyl complexes of platinum(II)". . p. 2110 - 2116. Retrieved 2008/10/08.