90065-11-5

Basic information

• Product Name: trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)
• Synonyms: trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)
• CAS NO: 90065-11-5
• Molecular Weight: 459.795
• Mol File: 90065-11-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)(90065-11-5)
• EPA Substance Registry System: trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II)(90065-11-5)

Safety Data

• Hazardous Substances Data: 90065-11-5(Hazardous Substances Data)

Upstream product

• 116563-64-5 trans-neopentyl(trifluoromethanesulfonato)bis(trimethylphosphine)platinum(II) 
• 116563-65-6 (trifluoromethanesulfonato)bis(trimethylphosphine)(phenyl)platinum(II) 
• 139-08-2 benzyldimethyltetradecylammonium chloride 
• 1076-43-3 benzene-d6 
• 90065-11-5 [PtCl(Ph)(PMe₃)2] 
• 108-86-1 bromobenzene 
• 19471-47-7 cis-dichlorobis(trimethylphosphine)platinum(II) 
• 2923-28-6 silver trifluoromethanesulfonate 
• 143-66-8 sodium tetraphenyl borate 
• 192936-51-9 trans-[PtBr(Ph)(PMe₃)2] 
• 594-09-2 trimethylphosphane 
• 52595-91-2 cis-[Pt(C₆H₅)2(P(CH₃)3)2] 

Downstream Products

• 76125-03-6 trans-hydrido(phenyl)bis(trimethylphosphino)platinum(II) 
• 90065-03-5 trans-mer-trihydridophenylbis(trimethylphosphine)platinum(IV) 
• 192936-46-2 [(PMe3)2(Ph)Pt(μ-H)Pt(Ph)(PMe3)2](CF3SO3) 
• 193023-71-1 [(PMe3)2(Ph)Pt(μ-H)Pt(Ph)(PMe3)2][B(C6H5)4] 
• 192936-51-9 trans-[PtBr(Ph)(PMe₃)2] 
• 343236-57-7 trans-[Pt(C₆H₅)CO(P(CH₃)3)2]BF₄ 

Relevant articles and documents

Experimental and theoretical studies on the course of CO insertion into Pt-C and Pd-C bonds in neutral and cationic complexes, [MR(Cl){P(CH3)3}2] and [MR{P(CH3)3}2(s)]+BF 4<

Behavior of neutral and cationic cis- and trans-monoorganoplatinum complexes has been examined and compared with that of the corresponding monoorganopalladium complexes. The cis- and trans-monoorganoplatinum complexes having two trimethylphosphine ligands

Reaction of organoboron compounds with platinum(II) disolvento complexes

Cationic complexes cis-[Pt(S)2L2]2+ (L = PMe3, PEt3, or PPh3; S = H2O or MeOH) react with arylboron derivatives ([BPh4]-, [B(p-Tol)4]-, [B(m-Tol)4]-, BPh3, B(OMe)Ph2, B(OMe)2Ph, and B(OH)2Ph) to give trans-[Pt(Ar)(S)L2]+ which are isolated and characterized as their halo derivatives trans-[PtX(Ar)L2]. When L = PMe3, the transient formation of cis-[Pt(Ar)(S)L2]+ is also observed. The cation cis-[Pt(CH3CN)2-(PEt3)2] 2+, however, reacts with [BPh4]- only when at least some of the solvent is hydroxylic. However the phenylation and cis-trans isomerization reactions are slowed down so that the intermediate formation of cis-[Pt(Ph)(CH3CN)(PEt3)2]+ cation can be observed. It is shown that [BPh4]- is not the phenylating agent as it decomposes to BPh3 and C6H6 prior to the phenylation reaction. Other phenylboron derivatives such as BPh3, B(OMe)Ph2, B(OMe)2Ph, and B(OH)2Ph can transfer all of their phenyl groups to platinum. It is found that the phenyl transfer is strictly regioselective; i.e., only the C atom bonded to boron is found coordinated to platinum. When [B(Me)(Ph)3]- is used, either a methyl or a phenyl group can be transferred to platinum.