Cr((C₆H₅)2C₅H₃S(CH₃))(CO)3

Base Information

Chemical Name:Cr((C₆H₅)2C₅H₃S(CH₃))(CO)3
CAS No.:76900-60-2
Molecular Formula:C₂₁H₁₆CrO₃S
Molecular Weight:400.418
Hs Code.:

Cr((C<sub>6</sub>H<sub>5</sub>)2C<sub>5</sub>H<sub>3</sub>S(CH<sub>3</sub>))(CO)3

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Cr((C₆H₅)2C₅H₃S(CH₃))(CO)3

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Technology Process of Cr((C₆H₅)2C₅H₃S(CH₃))(CO)3

There total 1 articles about Cr((C₆H₅)2C₅H₃S(CH₃))(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.6%

: 16800-46-7,22736-49-8
trisacetonitrile(tricarbonyl)chromium⁽⁰⁾

: 28275-94-7
1-Methyl-3,5-diphenyl-2H-thinium-tetrafluoroborat

: 76900-60-2,82796-27-8
anti-Tricarbonyl(1-methyl-3,5-diphenyl-.lamda.⁽⁴⁾-thiabenzol)chrom⁽⁰⁾

Guidance literature:: With KOt-Bu; In dimethyl sulfoxide; stirred under N2 at room temp. for 1.5 h; evapd. (0.1 torr), CHCl3 added, filtered on silica gel, filtrate concd., methylcyclohexane added, concd., petrolether added, filtered, washed (petroether), dried (20°C/0.1 torr, 20 min), elem. anal.;

Reference yield: 76.2%

: 76900-60-2,82796-27-8
anti-Tricarbonyl(1-methyl-3,5-diphenyl-.lamda.⁽⁴⁾-thiabenzol)chrom⁽⁰⁾

: 100-39-0
benzyl bromide

: 82782-95-4
anti-Tricarbonyl[3,5-diphenyl-1-(2-phenylethyl)-.lamda.⁽⁴⁾-thiabenzol]tricarbonylchrom⁽⁰⁾

Guidance literature:: With t-BuLi; In tetrahydrofuran; hexane; under N2 t-BuLi/hexane added to Cr-complex at -70°C, stirred for5 min, benzyl bromide added, allowed to room temp.; concd., CHCl3 added, filtered on silica gel, filtrate concd., methylcyclohexane added, concd., petroether added, filtered, washed (petroether),dried (20°C/0.1 torr), elem. anal.;

Reference yield: 73.9%

: 76900-60-2,82796-27-8
anti-Tricarbonyl(1-methyl-3,5-diphenyl-.lamda.⁽⁴⁾-thiabenzol)chrom⁽⁰⁾

: 106-95-6
allyl bromide

: 82782-94-3
anti-[1-(3-Butenyl)-3,5-diphenyl-.lamda.⁽⁴⁾-thiabenzol]tricarbonylchrom⁽⁰⁾

Guidance literature:: With t-BuLi; In tetrahydrofuran; hexane; under N2 t-BuLi/hexane added to Cr-complex at -70°C, stirred for5 min, allyl bromide added, allowed to room temp.; concd., CHCl3 added, filtered on silica gel, filtrate concd., methylcyclohexane added, concd., petroether added, filtered, washed (petroether),dried (20°C/0.1 torr), elem. anal.;