η1-(2-PhC6H4CH2C(O))Co(CO)3PPh3

Base Information

• Chemical Name: η1-(2-PhC6H4CH2C(O))Co(CO)3PPh3
• CAS No.: 634599-80-7
• Molecular Formula: C₃₅H₂₆CoO₄P
• Molecular Weight: 600.556
• Mol file: 634599-80-7.mol

Synonyms:

Chemical Property of η1-(2-PhC6H4CH2C(O))Co(CO)3PPh3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of η1-(2-PhC6H4CH2C(O))Co(CO)3PPh3

There total 1 articles about η1-(2-PhC6H4CH2C(O))Co(CO)3PPh3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.2%

sodium tetracarbonyl cobaltate (14878-28-5) + 2-phenylbenzyl bromide (19853-09-9) + triphenylphosphine (603-35-0) → η1-(2-PhC6H4CH2C(O))Co(CO)3PPh3 (634599-80-7)

Guidance literature:

With CO; In diethyl ether; byproducts: NaBr; 2-phenylbenzylbromide added to soln. of NaCo(CO)4 under Ar (stirring, -30°C); stirred (30 min, -30°C); warmed to room temp.; stirred (1-2 h); treated with CO; stirred (3 h); Et2O evapd.; recrystd. from Et2O/n-hexane;

DOI:10.1016/S1381-1169(03)00303-0

Reference yield:

η1-(2-PhC6H4CH2C(O))Co(CO)3PPh3 (634599-80-7) → η1-(2-PhC6H4CH2)Co(CO)3PPh3 (634599-81-8)

Guidance literature:

In diethyl ether; 32°C, 8 h, under Ar;

DOI:10.1016/S1381-1169(03)00303-0

upstream raw materials:

sodium tetracarbonyl cobaltate

2-phenylbenzyl bromide

triphenylphosphine

Downstream raw materials:

η1-(2-PhC6H4CH2)Co(CO)3PPh3