5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride

Base Information

• Chemical Name: 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride
• CAS No.: 478554-93-7
• Molecular Formula: C₄₄H₂₈ClFeN₄O₄
• Molecular Weight: 768.031
• Mol file: 478554-93-7.mol

Synonyms:

Chemical Property of 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride

There total 4 articles about 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.6%

iron(II) chloride tetrahydrate + 5,10,15,20-tetrakis(4'-hydroxyphenyl)porphyrin (51094-17-8) → 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride (64413-57-6,478554-93-7)

Guidance literature:

In N,N-dimethyl-formamide; for 0.5h; Reflux;

DOI:10.1021/op060056z

Reference yield: 59.0%

5,10,15,20-tetrakis(4-hydroxy phenyl)-21H,23H porphine (51094-17-8) + iron(II) chloride tetrahydrate → 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride (64413-57-6,478554-93-7)

Guidance literature:

With 2,6-dimethylpyridine; In N,N-dimethyl-formamide; mixt. of porphine, Fe salt and 2,6-lutidine in DMF was stirred at 95°C for 2 h under N2; cooled to room temp.; aq. HCl added; collected; washed (H2O); chromd. (silica gel, ethyl acetate/hexane, 2/1);

DOI:10.1246/bcsj.78.356

Reference yield:

5,10,15,20-tetrakis(4-hydroxy phenyl)-21H,23H porphine (51094-17-8) + iron(III) chloride (7705-08-0) → 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphinato iron(III) chloride (64413-57-6,478554-93-7)

Guidance literature:

In N,N-dimethyl-formamide; FeCl3 and the free-base porphyrin refluxed in DMF for 1 h according to the standard method (J. W. Buchler et al. Justus Liebigs Ann. Chem. 745 (1971) 135); metalloporphyrin precipitated by adding water and separated from solventon Buchner funnel;

DOI:10.1016/j.jpcs.2004.07.008

upstream raw materials:

5,10,15,20-tetrakis(4-hydroxy phenyl)-21H,23H porphine

iron(III) chloride

5,10,15,20-tetrakis(4'-hydroxyphenyl)porphyrin

Downstream raw materials:

(N-MeIm)Fe(II)(TPP-p-OH)(CO)

(N-MeIm)Fe(II)(TPP-p-OH)(⁽¹³⁾CO)