(+/-)-iso-β-peltatine

Base Information

Chemical Name:(+/-)-iso-β-peltatine
CAS No.:477-50-9
Molecular Formula:C₂₂H₂₂O₈
Molecular Weight:414.412
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-iso-β-peltatine

Chemical Property:

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Technology Process of (+/-)-iso-β-peltatine

There total 27 articles about (+/-)-iso-β-peltatine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 82299-45-4
(5aR,8aR)-10-Benzyloxy-5-(3,4,5-trimethoxy-phenyl)-5,8,8a,9-tetrahydro-5aH-furo[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6-one

: 477-50-9,518-29-6,641-25-8,82336-50-3
(+/-)-iso β-peltatine

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; at 20 ℃; for 18h; under 3800 Torr;
DOI:10.1016/S0040-4039(00)86991-9

Reference yield: 80.0%

: 82299-45-4
O-benzyl (+/-)-iso-β-peltatine

: 477-50-9,518-29-6,641-25-8,82336-50-3
(+/-)-iso-β-peltatine

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; for 18h; under 3750.3 Torr; Ambient temperature;
DOI:10.1016/S0040-4020(01)83505-5

Reference yield:

: 7797-83-3
2H-benzo[d]1,3-dioxolane-4-carbaldehyde

: 477-50-9,518-29-6,641-25-8,82336-50-3
(+/-)-iso-β-peltatine

Guidance literature:: Multi-step reaction with 12 steps

1: m-chloroperbenzoic acid / CH₂Cl₂ / 36 h / Heating

2: 10percent KOH / methanol / 1.5 h / Ambient temperature

3: 98 percent / trifluoroacetate d argent, brome / CHCl₃ / 0.5 h / Ambient temperature

4: 1.) 1.6M n-BuLi / 1.) hexane, ether, reflux, 1.75 h; 2.) reflux, 45 min

5: 97 percent / K₂CO₃, NaI / ethanol / 16 h / Heating

6: 75 percent / NaOMe / methanol / 6 h / Heating

7: 1.) 2N KOH; 2.) CaCl₂, NaBH₄, 2.5M KOH / 1.) water; 2.) ethanol, 50 deg C, 1 h

8: 86 percent / H₂ / 5percent Pd/C / ethyl acetate / 18 h / 3800 Torr / Ambient temperature

9: 84 percent / K₂CO₃, NaI / acetone / 16 h / Heating

10: 71.25 percent / hexamethyldisilylamine, 1.6M n-BuLi / hexane; benzene / 0.05 h / 5 - 10 °C

11: 88 percent / trifluoroacetic acid / CH₂Cl₂ / 6 h / Ambient temperature

12: 80 percent / H₂ / 10percent Pd/C / ethyl acetate / 18 h / 3750.3 Torr / Ambient temperature

With potassium hydroxide; sodium tetrahydroborate; n-butyllithium; trifluoroacetate d argent; hydrogen; bromine; sodium methylate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; 1,1,1,3,3,3-hexamethyl-disilazane; trifluoroacetic acid; sodium iodide; calcium chloride; palladium on activated charcoal; In methanol; ethanol; hexane; dichloromethane; chloroform; ethyl acetate; acetone; benzene;
DOI:10.1016/S0040-4020(01)83505-5