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[1-(diphenylphosphino-κP)-1'-(oxo-κO)ferrocene][1-(diphenylphosphino-κP)-1'-(hydroxy)ferrocene]carbonylrhodium

Base Information
  • Chemical Name:[1-(diphenylphosphino-κP)-1'-(oxo-κO)ferrocene][1-(diphenylphosphino-κP)-1'-(hydroxy)ferrocene]carbonylrhodium
  • CAS No.:1246843-58-2
  • Molecular Formula:C45H37Fe2O3P2Rh
  • Molecular Weight:902.334
  • Hs Code.:
[1-(diphenylphosphino-κP)-1'-(oxo-κO)ferrocene][1-(diphenylphosphino-κP)-1'-(hydroxy)ferrocene]carbonylrhodium

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Chemical Property of [1-(diphenylphosphino-κP)-1'-(oxo-κO)ferrocene][1-(diphenylphosphino-κP)-1'-(hydroxy)ferrocene]carbonylrhodium
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Technology Process of [1-(diphenylphosphino-κP)-1'-(oxo-κO)ferrocene][1-(diphenylphosphino-κP)-1'-(hydroxy)ferrocene]carbonylrhodium

There total 1 articles about [1-(diphenylphosphino-κP)-1'-(oxo-κO)ferrocene][1-(diphenylphosphino-κP)-1'-(hydroxy)ferrocene]carbonylrhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With C4H9Li; In tetrahydrofuran; methanol; (Schlenk technique); addn. of hexane soln. of butyllithium to dry THF soln. of ferrocene deriv., stirring for 30 min, evapn., dissolving in dry THF, addn. to methanolic soln. of rhodium compd., stirring for 3 h; concg., filtration, washing with diethyl ether, drying in vac. to give monorhodium deriv., keeping filtrate for several ds, filtration, recrystn. (hot CH2Cl2) to give dirhodium compd., elem. anal.;
DOI:10.1039/c0dt00061b
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