1'-(diphenylphosphino)-1-hydroxyferrocene

Base Information

Chemical Name:1'-(diphenylphosphino)-1-hydroxyferrocene
CAS No.:729610-13-3
Molecular Formula:C₂₂H₁₉FeOP
Molecular Weight:386.213
Hs Code.:

Synonyms:

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Chemical Property of 1'-(diphenylphosphino)-1-hydroxyferrocene

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Technology Process of 1'-(diphenylphosphino)-1-hydroxyferrocene

There total 1 articles about 1'-(diphenylphosphino)-1-hydroxyferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 1293-65-8
1,1'-dibromoferrocene

: 7732-18-5
water

: 729610-13-3
1'-(diphenylphosphino)-1-hydroxyferrocene

Guidance literature:: With n-butyllithium; bis(trimethylsilyl)peroxide; In tetrahydrofuran; (N2); using Schlenk techniques; dissolving of Fe(C5H4Br)2 in dry THF; cooling to -78°C; addn. of soln. of n-BuLi in hexane; stirring at -78°C for 10 min; addn. of (TMSO)2; stirring at -78°C for 1h; addn. of H2O; stirring vigorously; addn. of N2-satd. Et2O; sepn., re-extn. of aq. layer with Et2O; drying of combined org. layers (Na2SO4); removal of the solvent in vac., chromy.(silica, hexane:EtOAc 2:1); elem. anal.;
DOI:10.1039/b403862b

Reference yield: 65.0%

: di(rhodium)tetracarbonyl dichloride

: 729610-13-3
1'-(diphenylphosphino)-1-hydroxyferrocene

: 1246843-58-2
[1-(diphenylphosphino-κP)-1'-(oxo-κO)ferrocene][1-(diphenylphosphino-κP)-1'-(hydroxy)ferrocene]carbonylrhodium

: 1246843-59-3
[(1-(diphenylphosphino-κP)-1'-(μ-oxo)ferrocene)-carbonylrhodium(II)]2

Guidance literature:: With C₄H₉Li; In tetrahydrofuran; methanol; (Schlenk technique); addn. of hexane soln. of butyllithium to dry THF soln. of ferrocene deriv., stirring for 30 min, evapn., dissolving in dry THF, addn. to methanolic soln. of rhodium compd., stirring for 3 h; concg., filtration, washing with diethyl ether, drying in vac. to give monorhodium deriv., keeping filtrate for several ds, filtration, recrystn. (hot CH2Cl2) to give dirhodium compd., elem. anal.;
DOI:10.1039/c0dt00061b

Reference yield: 56.0%

: zirconium chloride-tetrahydrofuran

: 729610-13-3
1'-(diphenylphosphino)-1-hydroxyferrocene

: 1246843-61-7
bis[1'-(oxo-κO)ferrocenediyldiphenylphosphonium chloride]dichlorozirconium(IV)

Guidance literature:: In tetrahydrofuran; (Schlenk technique); addn. of THF soln. of ferrocene deriv. to THF soln.of zirconium compd., stirring at room temp. for 15 hs; evapn., washing with dry heptane, filtration, drying in vac., NMR and MS;
DOI:10.1039/c0dt00061b