cis-[(1,2-bis(dicyclohexylphosphino)ethane)Pt(PPhH*BH₃)2]

Base Information

• Chemical Name: cis-[(1,2-bis(dicyclohexylphosphino)ethane)Pt(PPhH*BH₃)2]
• CAS No.: 845752-21-8
• Molecular Formula: C₃₈H₆₆B₂P₄Pt
• Molecular Weight: 863.539
• Mol file: 845752-21-8.mol

Synonyms:

Chemical Property of cis-[(1,2-bis(dicyclohexylphosphino)ethane)Pt(PPhH*BH₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[(1,2-bis(dicyclohexylphosphino)ethane)Pt(PPhH*BH₃)2]

There total 2 articles about cis-[(1,2-bis(dicyclohexylphosphino)ethane)Pt(PPhH*BH₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

n-butyllithium (109-72-8,29786-93-4) + dichloro{bis(dicyclohexylphosphino)ethane}platinum(II) (90667-70-2) + diphenylphosphineborane (41593-58-2) → cis-[(1,2-bis(dicyclohexylphosphino)ethane)Pt(PPhH*BH3)2] (845752-21-8,847369-65-7)

Guidance literature:

In tetrahydrofuran; hexane; dichloromethane; under N2 atm. soln. BuLi in hexane was added dropwise to soln. PhPH2*BH3in THF at 0°C, warmed to 25°C and added dropwise to soln. cis-(PtCl2(dcype)) in CH2Cl2 at 25°C, stirred for 18 h; volatiles were removed, residue was dissolved in CH2Cl2 and filtered, hexane was added, solvent was removed, crystn. from CH2Cl2-hexane(1:1) at 25°C;

DOI:10.1039/b416114a

Reference yield:

1,2-bis-(dicyclohexylphosphino)ethane (23743-26-2) → cis-[(1,2-bis(dicyclohexylphosphino)ethane)Pt(PPhH*BH3)2] (845752-21-8,847369-65-7)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: tetrahydrofuran; dichloromethane; hexane

In tetrahydrofuran; hexane; dichloromethane;

DOI:10.1039/b416114a

upstream raw materials:

n-butyllithium

dichloro{bis(dicyclohexylphosphino)ethane}platinum(II)

diphenylphosphineborane

1,2-bis-(dicyclohexylphosphino)ethane