dichloro{bis(dicyclohexylphosphino)ethane}platinum(II)

Base Information

• Chemical Name: dichloro{bis(dicyclohexylphosphino)ethane}platinum(II)
• CAS No.: 90667-70-2
• Molecular Formula: C₂₆H₄₈Cl₂P₂Pt
• Molecular Weight: 688.601
• Mol file: 90667-70-2.mol

Synonyms:dichloro{bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property of dichloro{bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro{bis(dicyclohexylphosphino)ethane}platinum(II)

There total 13 articles about dichloro{bis(dicyclohexylphosphino)ethane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + cis-(methylsulfinato)methyl[bis(dicyclohexylphosphino)ethane]platinum(II) (220216-02-4) → dichloro{bis(dicyclohexylphosphino)ethane}platinum(II) (90667-70-2)

Guidance literature:

In tetrahydrofuran-d8; water; byproducts: MeSO2H, CH4; N2-atmosphere, NMR tube, 12 M HCl (aq.); room temp. (4 h);

DOI:10.1021/om980772s

Reference yield: 98.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + 1,2-bis-(dicyclohexylphosphino)ethane (23743-26-2) → dichloro{bis(dicyclohexylphosphino)ethane}platinum(II) (90667-70-2)

Guidance literature:

In dichloromethane; under N2 atm. to soln. (PhCN)2PtCl2 in CH2Cl2 soln. dcype in CH2Cl2 was added dropwise at 25°C and stirred for 4 h; volatiles were removed;

DOI:10.1039/b416114a

Reference yield: 86.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,2-bis-(dicyclohexylphosphino)ethane (23743-26-2) → dichloro{bis(dicyclohexylphosphino)ethane}platinum(II) (90667-70-2)

Guidance literature:

In dichloromethane; reaction of dichloro(1,5-cyclooctadiene)platinum(II) and bis(dicyclohexylphosphino)ethane in CH2Cl2 at room temp. for ca. 4 h; solvent removed by evapn., recrystn. from hot hexane/CHCl3, needles by cooling at -10°C;

DOI:10.1021/ja00213a016

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

1,2-bis-(dicyclohexylphosphino)ethane

dichloro(1,5-cyclooctadiene)platinum(ll)

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

Downstream raw materials:

cis-[Pt(1,2-bis(dicyclohexylphosphanyl)ethane)(H)(CN)]

cis-[Pt(1,2-bis(dicyclohexylphosphanyl)ethane)(Cl)(CN)]

[Pt₂(1,2-bis(dicyclohexylphosphanyl)ethane)2(H)3]BF₄

[Pt2(1,2-bis(dicyclohexylphosphanyl)ethane)2(μ-CO)(μ-H)]Cl