{Ir(diphpyH)H(P-n-Bu₃)2}SbF₆

Base Information

• Chemical Name: {Ir(diphpyH)H(P-n-Bu₃)2}SbF₆
• CAS No.: 137466-30-9
• Molecular Formula: C₄₁H₆₇IrNP₂*F₆Sb
• Molecular Weight: 1063.9
• Mol file: 137466-30-9.mol

Synonyms:

Chemical Property of {Ir(diphpyH)H(P-n-Bu₃)2}SbF₆

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of {Ir(diphpyH)H(P-n-Bu₃)2}SbF₆

There total 1 articles about {Ir(diphpyH)H(P-n-Bu₃)2}SbF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{Ir(COD)(P-n-Bu3)2}SbF6 (137466-32-1) + 2,6-diphenylpyridine (3558-69-8) → {Ir(diphpyH)H(P-n-Bu3)2}SbF6 (137466-30-9)

Guidance literature:

With H₂; In dichloromethane; byproducts: cyclooctane; dissolving of the COD complex salt in CH2Cl2, addn. of 2,6-diphpy to the red soln., cooling (0°C), bubbling H2 through the mixt. (5 min), color change from red to yellow, evapn. of solvent to 2 ml, addn. of diethyl ether, pptn.; filtration, washing (Et2O), drying (vac.), recrystn. (CH2Cl2/Et2O); elem. anal.;

DOI:10.1021/om00037a045

Reference yield:

{Ir(diphpyH)H(P-n-Bu3)2}SbF6 (137466-30-9) → hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}(dihydrogen)bis(tri-n-butylphosphine)iridium(III) hexafluoroantimonate (137466-42-3)

Guidance literature:

With H₂; In chloroform-d1; passing H2 through a cooled (0°C) soln. of the Ir complex salt in CDCl3 (5 min); detn. by (1)H-NMR;

DOI:10.1021/om00037a045

upstream raw materials:

{Ir(COD)(P-n-Bu₃)2}SbF₆

2,6-diphenylpyridine

Downstream raw materials:

hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}(dihydrogen)bis(tri-n-butylphosphine)iridium(III) hexafluoroantimonate