trans-[Rh(Cl(CO)(1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)2]

Base Information

Chemical Name:trans-[Rh(Cl(CO)(1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)2]
CAS No.:850694-71-2
Molecular Formula:C₃₃H₄₂ClO₇P₂Rh
Molecular Weight:750.998
Hs Code.:

Synonyms:

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Chemical Property of trans-[Rh(Cl(CO)(1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)2]

Chemical Property:

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Technology Process of trans-[Rh(Cl(CO)(1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)2]

There total 2 articles about trans-[Rh(Cl(CO)(1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: di(rhodium)tetracarbonyl dichloride

: 97739-46-3
1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

: 850694-71-2,850796-54-2
trans-[Rh(Cl(CO)(1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)2]

Guidance literature:: In dichloromethane; (N2); using Schlenk techniques; dissolving of Rh2(CO)4Cl2 in CH2Cl2; treatment with soln. of Me4C6H4O3PPh in CH2Cl2; monitoring by NMR; further addn. of soln. of Me4C6H4O3PPh in CH2Cl2; concn., pptn., elem. anal.;
DOI:10.1039/b418259f

Reference yield:

: RhC₃*3H₂O

: 97739-46-3
1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

: 850694-71-2,850796-54-2
trans-[Rh(Cl(CO)(1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)2]

Guidance literature:: With formaldehyde; In ethanol; (N2); using Schlenk techniques; warming of RhCl3*3H2O and excess of Me4C6H4O3PPh in ethanol and formaldehyde; cooling in ice, pptn., drying under vac., as mixt. of rac- and meso-diastereoisomers; elem. anal.;
DOI:10.1039/b418259f