[Au(CCCCH)(P(C₆H₄CH₃)3)]

Base Information

Chemical Name:[Au(CCCCH)(P(C₆H₄CH₃)3)]
CAS No.:877072-09-8
Molecular Formula:C₂₅H₂₂AuP
Molecular Weight:550.39
Hs Code.:

[Au(CCCCH)(P(C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)3)]

Synonyms:

Suppliers and Price of [Au(CCCCH)(P(C₆H₄CH₃)3)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Au(CCCCH)(P(C₆H₄CH₃)3)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Au(CCCCH)(P(C₆H₄CH₃)3)]

There total 1 articles about [Au(CCCCH)(P(C₆H₄CH₃)3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 460-12-8,27987-87-7
Butadiyne

: 28978-10-1
(tri-p-tolylphosphine)gold(I) chloride

: 877072-09-8
[Au(CCCCH)(P(C₆H₄CH₃)3)]

Guidance literature:: With CuI; In tetrahydrofuran; diethylamine; (N2); CuI was added to soln. of Au complex in THF/Et2NH; soln. of alkynein THF was added; mixt. was stirred at room temp. for 30 min; solvent removed; extd. (CH2Cl2); chromd. (SiO2, CH2Cl2); hexane added; concd.; elem. anal.;
DOI:10.1016/j.jorganchem.2005.08.050

Reference yield: 78.0%

: 28978-10-1
(tri-p-tolylphosphine)gold(I) chloride

: 877072-09-8
[Au(CCCCH)(P(C₆H₄CH₃)3)]

: 558482-39-6
(Au[P(tol)3])2(μ-(CC)2)

Guidance literature:: With CuI; In tetrahydrofuran; diethylamine; (N2); mixt. of Au complexes (1/1) and CuI in THF/NHEt2 in Schlenk flask was stirred at room temp. for 1 h; filtered; solvent removed; extd. (CH2Cl2); chromd. (SiO2, CH2Cl2/hexane,1/1);
DOI:10.1016/j.jorganchem.2005.08.050

Reference yield: 62.0%

: 37701-76-1
chloro-tris(diphenylphosphinomethyl)ethane-copper

: 877072-09-8
[Au(CCCCH)(P(C₆H₄CH₃)3)]

: [((CH₃C₆H₄)3P)Au(CCCC)Cu(CH₃C(CH₂P(C₆H₅)2)3)]

Guidance literature:: With n-BuLi; In tetrahydrofuran; hexane; (N2); soln. of BuLi in hexane was added to soln. of Au complex in THF at-100°C; stirred for 15 min; Cu complex was added; suspn. was war med to room temp.; soln. was stirred at room temp. for 3.5 h; solvent removed; extd. (CH2Cl2); filtered into cold hexane; filtered; washed (Et2O, pentane); air-dried; elem. anal.;
DOI:10.1016/j.jorganchem.2005.08.050