bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate

Base Information

Chemical Name:bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate
CAS No.:106223-26-1
Molecular Formula:C₃₇H₂₅BrO₂Rh*Cl₃Zn
Molecular Weight:856.163
Hs Code.:

Synonyms:

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Chemical Property of bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate

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Technology Process of bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate

There total 1 articles about bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: tetracarbonyldi-μ-chlorodirhodium(I)

: 56849-84-4
1-bromo-1,2,3,4,5-pentaphenylcyclopenta-2,4-diene

: 7440-66-6
zinc

: 106223-26-1
bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate

Guidance literature:: In benzene; (dry N2); mixt. stirred (24 h, room temp.); ppt. filtered off, washed (toluene), and recrystd. (CH2Cl2/n-hexane); elem. anal.;
DOI:10.1039/DT9860001613

Reference yield: 31.0%

: 106223-26-1
bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate

: Rh(CO)(P(C₆H₅)3)(C₅(C₆H₅)5)*xC₄H₈O

Guidance literature:: With tetrahydrofuran; triphenylphosphine; In dichloromethane; byproducts: Mn2(CO)10; (dry N2); soln. of (RhBr(CO)2(C5Ph5))(ZnCl3) and PPh3 stirred for 20 min to form (RhBr(CO)(PPh3)(C5Ph5))(ZnCl3); (N(P(C6H5)3)2)(Mn(CO)5) added; resulting soln. concd. (vac.) and chromd. (alumina): elution (n-hexane)gave Mn2(CO)10, further elution (CH2Cl2/n-hexane 1/1), evapn. of this eluate gave Rh(CO)(PPh3)(C5Ph5) as solid "analysed as a THF solvate (elem. anal.)" (THF ?); mass spectrum;
DOI:10.1039/DT9860001613

Reference yield: 8.0%

: 106223-26-1
bromodicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium(III) trichlorozincate

: 603-32-7
triphenyl-arsane

: Rh(CO)(As(C₆H₅)3)(C₅(C₆H₅)5)*0.5CH₂Cl₂

Guidance literature:: With dichloromethane; In dichloromethane; byproducts: Mn2(CO)10; (dry N2); soln. of (RhBr(CO)2(C5Ph5))(ZnCl3) and AsPh3 stirred for 20 min to form (RhBr(CO)(AsPh3)(C5Ph5))(ZnCl3); (N(P(C6H5)3)2)(Mn(CO)5) added; resulting soln. concd. (vac.) and chromd. (alumina): elution (n-hexane)gave Mn2(CO)10, further elution (CH2Cl2/n-hexane 1/1), evapn. of this eluate gave Rh(CO)(AsPh3)(C5Ph5)*0.5CH2Cl2; elem. anal.; mass spectrum;
DOI:10.1039/DT9860001613