[uranium(V)chloride(HC(SiMe₂N(3,5-Me₂C₆H₃))3)(THF)]

Base Information

Chemical Name:[uranium(V)chloride(HC(SiMe₂N(3,5-Me₂C₆H₃))3)(THF)]
CAS No.:1242471-92-6
Molecular Formula:C₃₅H₅₄ClN₃OSi₃U
Molecular Weight:890.572
Hs Code.:

[uranium(V)chloride(HC(SiMe<sub>2</sub>N(3,5-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>))3)(THF)]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [uranium(V)chloride(HC(SiMe₂N(3,5-Me₂C₆H₃))3)(THF)]

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Technology Process of [uranium(V)chloride(HC(SiMe₂N(3,5-Me₂C₆H₃))3)(THF)]

There total 1 articles about [uranium(V)chloride(HC(SiMe₂N(3,5-Me₂C₆H₃))3)(THF)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: HC(Si(CH₃)2NLiC₆H₃(CH₃)2)3(O(C₂H₅)2)

: 10026-10-5
uranium(IV) chloride

: 1242471-92-6
[UCl(THF)(tris(N-(3,5-dimethylphenyl)amido-dimethylsilyl)methane)]

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; (Schlenk, N2) THF was added slowly to a cold (-78°C) stirring mixt. of amide-compound and UCl4, the mixt. was allowed to warm to room temp. slowly over 16 h, the soln. was heated to reflux for 2-3 min, allowedto cool to room temp. with stirring; volatiles were removed in vac., extd. into hot toluene, filtered, volatiles were removed in vac., the residue was washed with cold hexane (-78°C); elem. anal.;
DOI:10.1039/b926018h

Reference yield: 85.0%

: 16029-98-4
trimethylsilyl iodide

: 1242471-92-6
[UCl(THF)(tris(N-(3,5-dimethylphenyl)amido-dimethylsilyl)methane)]

: 1242471-94-8
[UI(THF)2(tris(N-(3,5-dimethylphenyl)amido-dimethylsilyl)methane)]

Guidance literature:: In toluene; byproducts: (CH3)3SiCl; (Schlenk, N2) (CH3)3SiI was added dropwise to a cold (-78°C) stirring slurry of complex in toluene, allowed to warm to room temp. over 16h, heated to reflux for 2 min, allowed to cool to room temp.; volatiles were removed in vac., extd. into hexane, allowed to stand at -30°C for 16 h; elem. anal.;
DOI:10.1039/b926018h

Reference yield: 78.0%

: 1242471-92-6
[UCl(THF)(tris(N-(3,5-dimethylphenyl)amido-dimethylsilyl)methane)]

: 4111-55-1
lithium dicyclohexylamide

: 1242471-96-0
[U(THF)(NCy₂)(tris(N-(3,5-dimethylphenyl)amido-dimethylsilyl)methane)]

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; (Schlenk, N2) THF was added slowly to a cold (-78°C) stirring mixt. of complex and Li-amide, allowed to warm to room temp. over 16 h, heated to reflux for 2 min; volatiles were removed in vac., extd. into toluene, filtered, volatiles were removed in vac., recrystd. from hot hexane; elem. anal.;
DOI:10.1039/b926018h