hydridobis(thiobenzoato)bis(triphenylphosphine)iridium

Base Information

• Chemical Name: hydridobis(thiobenzoato)bis(triphenylphosphine)iridium
• CAS No.: 188746-28-3
• Molecular Formula: C₅₀H₄₁IrO₂P₂S₂
• Molecular Weight: 992.174
• Mol file: 188746-28-3.mol

Synonyms:

Chemical Property of hydridobis(thiobenzoato)bis(triphenylphosphine)iridium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydridobis(thiobenzoato)bis(triphenylphosphine)iridium

There total 1 articles about hydridobis(thiobenzoato)bis(triphenylphosphine)iridium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

thiobenzoic acid (98-91-9) + mer-trihydridotris(triphenylphosphine)iridium(III) → hydridobis(thiobenzoato)bis(triphenylphosphine)iridium (188746-28-3)

Guidance literature:

In toluene; reflux (ca. 40 min); filtration, concn., crystn. (CH2Cl2/MeOH); elem. anal.;

DOI:10.1039/a607011f

Reference yield: 84.0%

hydridobis(thiobenzoato)bis(triphenylphosphine)iridium (188746-28-3) + carbon monoxide (201230-82-2) → [IrH(CO)(S(O)CC6H5)2(P(C6H5)3)2]*0.5CH2Cl2

Guidance literature:

In toluene; refluxing the Ir complex for ca. 20 min with slow passage of CO; filtration, concn., crystn. (CH2Cl2/MeOH); elem. anal.;

DOI:10.1039/a607011f

Reference yield: 51.0%

thiobenzoic acid (98-91-9) + hydridobis(thiobenzoato)bis(triphenylphosphine)iridium (188746-28-3) → tris(thiobenzoato)bis(triphenylphosphine)iridium (188746-31-8)

Guidance literature:

In toluene; reflux (ca. 2 h); filtration, concn., crystn. (CH2Cl2/MeOH); elem. anal.;

DOI:10.1039/a607011f

upstream raw materials:

thiobenzoic acid

Downstream raw materials:

tris(thiobenzoato)bis(triphenylphosphine)iridium