[((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl]

Base Information

• Chemical Name: [((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl]
• CAS No.: 1332700-21-6
• Molecular Formula: C₂₃H₂₅ClPdS₂Si
• Molecular Weight: 535.542
• Mol file: 1332700-21-6.mol

Synonyms:

Chemical Property of [((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl]

There total 1 articles about [((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

tetrakis(acetonitrile)palladium(II) tetrafluoroborate (21797-13-7) + (3,5-bis(phenylthiomethyl)phenyl)trimethylsilane (1332700-23-8) + sodium chloride (7647-14-5) → [((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl] (1332700-21-6)

Guidance literature:

In acetonitrile; (N2, Schlenk technique); addn. of palladium compd. to CH3CN soln. of silane deriv., stirring for 16 h at reflux, filtration through celite, avapn., addn. of mixt. of aq. satd. soln. of NaCl and CH2Cl2, stirring for 1h; separating organic phase, drying over MgSO4, evapn., chromy. (CH2Cl2), addn. of polyvinylpyrrolidone, stirring for 2 h, filtration through celite, evapn., MS;

DOI:10.1039/c1dt10502g

upstream raw materials:

tetrakis(acetonitrile)palladium(II) tetrafluoroborate

(3,5-bis(phenylthiomethyl)phenyl)trimethylsilane

sodium chloride