[1,3-C₆H₄(OPPh₂AuCl)2]

Base Information

• Chemical Name: [1,3-C₆H₄(OPPh₂AuCl)2]
• CAS No.: 279214-82-3
• Molecular Formula: C₃₀H₂₄Au₂Cl₂O₂P₂
• Molecular Weight: 943.306
• Mol file: 279214-82-3.mol

Synonyms:

Chemical Property of [1,3-C₆H₄(OPPh₂AuCl)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,3-C₆H₄(OPPh₂AuCl)2]

There total 1 articles about [1,3-C₆H₄(OPPh₂AuCl)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + 1,3-bis(diphenylphosphinito)benzene (279214-81-2) → [1,3-C6H4(OPPh2AuCl)2] (279214-82-3)

Guidance literature:

In tetrahydrofuran; under N2; soln. of ligand in THF added to soln. of 2 equiv. of Au compd. in THF; stirred for 1 h; solvent removed under vac,; washed with ether and pentane; elem. anal.;

DOI:10.1021/ic991497k

Reference yield: 54.0%

[1,3-C6H4(OPPh2AuCl)2] (279214-82-3) + thiophenol (108-98-5) → [1,3-C6H4(OPPh2AuSC6H5)2] (279214-83-4)

Guidance literature:

With triethyl amine; In tetrahydrofuran; under N2; 2 equiv. of Et3N and 2 equiv. of benzenethiol added to soln. of Au complex in THF at 0°C; stirred for 3 h; filtered through sintered glass funnel; solvent removed under vac.; washed with ether and pentane; elem. anal.;

DOI:10.1021/ic991497k

Reference yield:

[1,3-C6H4(OPPh2AuCl)2] (279214-82-3) + thiophenol (108-98-5) → [(Au2(μ-SPh)(PPh2O)(PPh2OH))2]

Guidance literature:

Multi-step reaction with 2 steps

1: triethyl amine / tetrahydrofuran

2: acetone

With triethyl amine; In tetrahydrofuran; acetone;

DOI:10.1021/ic991497k

upstream raw materials:

chloro(dimethylsulfide) gold(I)

1,3-bis(diphenylphosphinito)benzene

Downstream raw materials:

[1,3-C₆H₄(OPPh₂AuSC₆H₅)2]