Pocop

Base Information

Chemical Name:Pocop
CAS No.:279214-81-2
Molecular Formula:C30H24O2P2
Molecular Weight:478.467
Hs Code.:
UNII:RV3YH2Y6FP
DSSTox Substance ID:DTXSID301241325
Nikkaji Number:J1.351.195K
Wikipedia:POCOP
Wikidata:Q7119907

Synonyms:POCOP;RV3YH2Y6FP;1,3-Bis(diphenylphosphinito)benzene;UNII-RV3YH2Y6FP;279214-81-2;P,P-1,3-Phenylene bis(P,P-diphenylphosphinite);Phosphinous acid, diphenyl-, 1,3-phenylene ester;Phosphinous acid, P,P-diphenyl-, P,P-1,3-phenylene ester;SCHEMBL1465968;DTXSID301241325;1,3-bis(diphenylphosphinooxy)benzene;MFCD31720964;1,3-Bis(diphenylphosphinyloxy)benzene

Suppliers and Price of Pocop

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Pocop

Chemical Property:

XLogP3:7.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:8
Exact Mass:478.12515400
Heavy Atom Count:34
Complexity:478

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)OC3=CC(=CC=C3)OP(C4=CC=CC=C4)C5=CC=CC=C5

Technology Process of Pocop

There total 1 articles about Pocop which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 108-46-3
recorcinol

: 279214-81-2
1,3-bis(diphenylphosphinito)benzene

Guidance literature:: With triethylamine; In tetrahydrofuran; at 25 ℃; for 0.5h; Inert atmosphere;
DOI:10.1039/c1dt10381d

Reference yield: 88.0%

: 14515-44-7
NiBr₂(CH₃CN)₂

: 279214-81-2
1,3-bis(diphenylphosphinito)benzene

: 1303996-71-5
[(2,6-(Ph2PO)2C6H3-κ3C,P,P')NiBr]

Guidance literature:: In toluene; (N2); addn. of nickel compd. and triethylamine to stirred soln. of diphosphine deriv. in toluene, stirring at 25°C for 12 h; evapn., extn. (anhyd. CHCl3), filtration through silica gel, evapn. in vac., elem. anal.;
DOI:10.1039/c1dt10381d

Reference yield: 85.0%

: palladium(II) trifluoroacetate

: 279214-81-2
1,3-bis(diphenylphosphinito)benzene

: 315667-11-9
Pd(CH((C(OP(C₆H₅)2)CH)2CH))(OC(O)CF₃)

Guidance literature:: In tetrahydrofuran; under N2; soln. of Pd(OCOCF3)2 and resorcinolbis(diphenyl)phosphinite (1:1 mol) in THF stirred at room temp. 2 h; evapd. (vac.); residue washed (EtOH); crystd. (CH2Cl2-EtOH); elem. anal.;
DOI:10.1039/b004793g