Dibenzyldiphenylgermane

Base Information

• Chemical Name: Dibenzyldiphenylgermane
• CAS No.: 100184-65-4
• Molecular Formula: C₂₆H₂₄Ge
• Molecular Weight: 409.067
• Mol file: 100184-65-4.mol

Synonyms:

Chemical Property of Dibenzyldiphenylgermane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dibenzyldiphenylgermane

There total 4 articles about Dibenzyldiphenylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.3%

diphenylgermylenedipotassium (100184-59-6) + benzyl chloride (100-44-7) → benzyldiphenylgermane + diphenylgermane (1675-58-7) + Dibenzyldiphenylgermane (100184-65-4) + toluene (108-88-3,15644-74-3,16713-13-6)

Guidance literature:

With water; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; soln. of Ph2GeK2 in HMPA/THF added to PhCH2Cl, stirred at room temp. for 30 min, cooled with water bath, hydrolyzed; extd. with ether, org. layer dried over anhyd. Na2SO4, isolated by preparative GLC and TLC;

DOI:10.1246/bcsj.58.1443

Reference yield: 19.6%

diphenyldibromogermane (1080-42-8) + benzylmagnesium chloride (6921-34-2) → Dibenzyldiphenylgermane (100184-65-4)

Guidance literature:

In diethyl ether; Ph2GeBr2 in ether added to PhCH2MgCl in ether, stirred with reflux for 5 h, hydrolyzed; org. layer dried over CaCl2, evapd., fractionally distd.; elem. anal.;

DOI:10.1246/bcsj.58.1443

Reference yield: 2.4%

benzyl chloride (100-44-7) + (diphenylgermylene)dipotassium → Dibenzyldiphenylgermane (100184-65-4) + toluene (108-88-3,15644-74-3,16713-13-6)

Guidance literature:

In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; for 0.5h; Product distribution; Ambient temperature;

DOI:10.1246/bcsj.58.1443

upstream raw materials:

diphenyldibromogermane

benzyl chloride

diphenylgermylenedipotassium

benzylmagnesium chloride