bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridiumdifluoride tetrafluoroborate

Base Information

• Chemical Name: bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridiumdifluoride tetrafluoroborate
• CAS No.: 1239599-40-6
• Molecular Formula: BF₄*C₃₄H₃₈F₂IrP₂
• Molecular Weight: 825.645
• Mol file: 1239599-40-6.mol

Synonyms:

Chemical Property of bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridiumdifluoride tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridiumdifluoride tetrafluoroborate

There total 1 articles about bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridiumdifluoride tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

xenon difluoride (13709-36-9) + bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridium(I) tetrafluoroborate (38704-64-2) → bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridiumdifluoride tetrafluoroborate (1239599-40-6)

Guidance literature:

In dichloromethane; byproducts: xenon; (Schlenk, N2) Ir-complex and XeF2 were placed into separate passivated vials in dry box, evacuated, CH2Cl2 was transferred by distillation at -196°C, warmed, XeF2soln. was added at -196°C to complex, warmed to room temp., agatated; the soln. was removed in vac.; elem. anal.;

DOI:10.1039/c0dt00066c

upstream raw materials:

xenon difluoride

bis(methyldiphenylphosphine)(cycloocta-1,5-diene)iridium(I) tetrafluoroborate