(μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene

Base Information

• Chemical Name: (μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene
• CAS No.: 96998-70-8
• Molecular Formula: 2C₆H₆*C₄₂H₄₄Cl₃Fe₃N₁₂O₇
• Molecular Weight: 1259.01
• Mol file: 96998-70-8.mol

Synonyms:

Chemical Property of (μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene

There total 3 articles about (μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

sodium benzoate (532-32-1) + tetraethylammonium μ-oxohexachlorodiferrate(III) + 1,1,2-tris-(N-methyl-2-imidazolyl)-1-hydroxyethane + tetraethylammonium tetrachloridoferrate(III) → (μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene (96998-70-8)

Guidance literature:

In acetonitrile; addn. of 0.335mmol (Et4N)(FeCl4) to 0.336mmol of (Et4N)2(Fe2OCl6) in MeCN, then addn. of 0.673mmol of anhyd. Na(O2CPh), then after 1h, addn. of a soln., containing 0.681mmol polyimidazole ligand/1.4mmol Et3N in MeCN;coloring of soln.: deep red brown;; filtn. off of a white solid, removal of solvent in vacuo; further purification with MeCN; elem. anal.; react. mechanism. described;;

DOI:10.1021/ja00248a019

Reference yield:

sodium benzoate (532-32-1) + tetraethylammonium μ-oxohexachlorodiferrate(III) + tetraethylammonium tetrachloridoferrate(III) + 1,1,2-tris(N-methylimidazol-2-yl)-1-hydroxyethane (108694-99-1) → (μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene (96998-70-8)

Guidance literature:

With triethylamine; benzene; In acetonitrile; FeCl4 salt addied with stirring to a soln. of the Fe2OCl6 salt; addn. ofanhydrous sodium benzoate after 5 mi; after 1 h a soln. of the ligand and Et3N added dropwise the resulting brown suspn.; after 30 min a white solid filteree off; solvent removed;; purified by recrystn. from MeCN-C6H6; elem. anal.;;

DOI:10.1021/ja00301a045

Reference yield:

sodium benzoate (532-32-1) + tetraethylammonium μ-oxohexachlorodiferrate(III) + 1,1,2-tris-(N-methyl-2-imidazolyl)-1-hydroxyethane → (μ-oxo)bis(μ-benzoato)bis(μ-(1,1,2-tris(N-methylimidazol-2-yl)-ethane 1 oxide-N,N,O))trichlortriiron(III) dibenzene (96998-70-8)

Guidance literature:

In dichloromethane; acetonitrile; dissolving of 0.344mmol of corresponding iron complex in acetonitrile, aaddg. of anhyd. Na-benzoate while vigorous stirring, then (after 2.5h), adding of 0.688mmol of polyimidazole ligand (prep. given) in methylene chloride and further stirring (2h);; removal of white percipitate by filtn., addg. of CH2Cl2 and benzene and removal in vacuo twice; resulting brown solid was dissolved in dry MeCN, layering dry benzene on the top; crystals were obtained after 3 weeks;;

DOI:10.1021/ja00248a019

upstream raw materials:

sodium benzoate

1,1,2-tris(N-methylimidazol-2-yl)-1-hydroxyethane