Lithium, bicyclo[2.2.1]hept-1-yl-

Base Information

Chemical Name:Lithium, bicyclo[2.2.1]hept-1-yl-
CAS No.:930-81-4
Molecular Formula:C7H11 Li
Molecular Weight:102.105
Hs Code.:2902199090
DSSTox Substance ID:DTXSID2061307
Mol file:930-81-4.mol

Synonyms:930-81-4;Lithium, bicyclo[2.2.1]hept-1-yl-;Lithium, bicyclo(2.2.1)hept-1-yl-;1-Norbonyllithium;DTXSID2061307

Suppliers and Price of Lithium, bicyclo[2.2.1]hept-1-yl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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price

Total 4 raw suppliers

Chemical Property of Lithium, bicyclo[2.2.1]hept-1-yl-

Chemical Property:

Vapor Pressure:25.4mmHg at 25°C
Boiling Point:112.6°C at 760 mmHg
PSA：0.00000
LogP:2.26730
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:102.10207879
Heavy Atom Count:8
Complexity:72.5

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:[Li+].C1C[C-]2CCC1C2

Technology Process of Lithium, bicyclo[2.2.1]hept-1-yl-

There total 1 articles about Lithium, bicyclo[2.2.1]hept-1-yl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 765-67-3
1-chlorobicyclo[2.2.1]heptane

: 930-81-4
1-norbornyllithium

Guidance literature:: With lithium; In pentane; for 1h; Heating;
DOI:10.1016/S0040-4020(01)90451-X

Reference yield: 88.0%

: dipyridinium hexachlorocerate (IV)

: 930-81-4
1-norbornyllithium

: 2Li⁽¹⁺⁾*CeCl₆^(2-)*2C₅H₅N=Li₂[CeCl₆]*2C₅H₅N

: 279-23-2
norbornene

Guidance literature:: In diethyl ether; adding dropwise a soln. of 1-norbornyllithium to a suspn. of the Ce complex (-20°C, molar ratio Ce:Li = 1:2), slowly warming to room temp., color changing from orange to yellow, stirring (12 h); filtering, extg. (boiling pentane, 2 h), drying (vac.), norbornane fromthe filtrate (evapg., cooling (-78°C); elem. anal.;

Reference yield: 66.0%

: 115647-96-6,55333-16-9,19999-87-2
bis(tricyclohexylphosphine)nickel(II) dichloride

: 930-81-4
1-norbornyllithium

: 22829-35-2,25703-57-5
Ni(PCy₃)2HCl

: (PCy3)2Ni(η2-1-norbornene)

Guidance literature:: In pentane; ligand in pentane added to slurry of Ni complex in pentane; stirred for 10 min; passed over alumina pad; rinsed with pentane; solvent evapd. from filtrate; extd. with pentane; filtered over alumina pad; solvent removed; elem. anal.;
DOI:10.1021/om0503388