C₃₃H₄₃NOSSi

Base Information

• Chemical Name: C₃₃H₄₃NOSSi
• CAS No.: 86864-40-6
• Molecular Formula: C₃₃H₄₃NOSSi
• Molecular Weight: 529.862
• Mol file: 86864-40-6.mol

Synonyms:

Chemical Property of C₃₃H₄₃NOSSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₃H₄₃NOSSi

There total 5 articles about C₃₃H₄₃NOSSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylmethanethiol (3695-77-0) → C33H43NOSSi (86864-40-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 88 percent / Sulfuryl chloride / toluene; diethyl ether / 2 h / 0 °C

2: 78 percent / 29 percent NH₄OH/H₂O / CH₂Cl₂ / 0 °C

3: 70 percent / Pyridinium p-toluenesulfonate, (PPTS)/anhydr. MgSO₄ / CH₂Cl₂ / 7 h / Ambient temperature

4: 1.) sec-BuLi / 1.) THF/cyclohexane, -78 deg C, 90 min, 2.) THF, -78 deg C, 90 min

With ammonium hydroxide; sulfuryl dichloride; water; sec.-butyllithium; pyridinium p-toluenesulfonate; magnesium sulfate; In diethyl ether; dichloromethane; toluene;

DOI:10.1021/jo00168a031

Reference yield:

tritylsulfenyl chloride (24165-03-5) → C33H43NOSSi (86864-40-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 78 percent / 29 percent NH₄OH/H₂O / CH₂Cl₂ / 0 °C

2: 70 percent / Pyridinium p-toluenesulfonate, (PPTS)/anhydr. MgSO₄ / CH₂Cl₂ / 7 h / Ambient temperature

3: 1.) sec-BuLi / 1.) THF/cyclohexane, -78 deg C, 90 min, 2.) THF, -78 deg C, 90 min

With ammonium hydroxide; water; sec.-butyllithium; pyridinium p-toluenesulfonate; magnesium sulfate; In dichloromethane;

DOI:10.1021/jo00168a031

Reference yield:

Triphenylmethanesulfenamide (38499-08-0) → C33H43NOSSi (86864-40-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 70 percent / Pyridinium p-toluenesulfonate, (PPTS)/anhydr. MgSO₄ / CH₂Cl₂ / 7 h / Ambient temperature

2: 1.) sec-BuLi / 1.) THF/cyclohexane, -78 deg C, 90 min, 2.) THF, -78 deg C, 90 min

With sec.-butyllithium; pyridinium p-toluenesulfonate; magnesium sulfate; In dichloromethane;

DOI:10.1021/jo00168a031

upstream raw materials:

allyl iodid

5-<(tert-Butyldimethylsilyl)oxy>-2-pentanone Tritylsulfenimine

triphenylmethanethiol

tritylsulfenyl chloride