[Ru(OAc-κ¹O)(OAc-κ²O,O’)(PPh₃)3]

Base Information

• Chemical Name: [Ru(OAc-κ¹O)(OAc-κ²O,O’)(PPh₃)3]
• CAS No.: 136489-53-7
• Molecular Formula: C₅₈H₅₁O₄P₃Ru
• Molecular Weight: 1006.03
• Mol file: 136489-53-7.mol

Synonyms:

Chemical Property of [Ru(OAc-κ¹O)(OAc-κ²O,O’)(PPh₃)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(OAc-κ¹O)(OAc-κ²O,O’)(PPh₃)3]

There total 1 articles about [Ru(OAc-κ¹O)(OAc-κ²O,O’)(PPh₃)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + sodium acetate trihydrate (6131-90-4) → [Ru(OAc-κ1O)(OAc-κ2O,O’)(PPh3)3] (136489-53-7,75713-09-6)

Guidance literature:

In methanol; at 75 ℃; for 1.25h; Inert atmosphere;

DOI:10.1002/chem.201204270

Reference yield: 70.0%

[Ru(OAc-κ1O)(OAc-κ2O,O’)(PPh3)3] (136489-53-7,75713-09-6) → [Ru(κ1-OAc)(κ2-OAc)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)] (1459161-54-6)

Guidance literature:

With [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]; In toluene; at 113 ℃; for 3h; Inert atmosphere;

DOI:10.1002/chem.201204270

Reference yield:

[Ru(OAc-κ1O)(OAc-κ2O,O’)(PPh3)3] (136489-53-7,75713-09-6) → C45H47O5P3Ru

Guidance literature:

Multi-step reaction with 2 steps

1: [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] / toluene / 3 h / 113 °C / Inert atmosphere

2: dichloromethane; hexane / 20 °C / Inert atmosphere

With [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]; In hexane; dichloromethane; toluene;

DOI:10.1002/chem.201204270

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

sodium acetate trihydrate

Downstream raw materials:

[Ru(κ¹-OAc)(κ²-OAc)(κ³-1,1,1-tris(diphenylphosphinomethyl)ethane)]