Gd{(C₃H₇O)2PS₂}3{2C₆H₅CONH₂}

Base Information

Chemical Name:Gd{(C₃H₇O)2PS₂}3{2C₆H₅CONH₂}
CAS No.:93441-33-9
Molecular Formula:C₃₂H₅₆GdN₂O₈P₃S₆
Molecular Weight:1039.37
Hs Code.:

Gd{(C<sub>3</sub>H<sub>7</sub>O)2PS<sub>2</sub>}3{2C<sub>6</sub>H<sub>5</sub>CONH<sub>2</sub>}

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Chemical Property of Gd{(C₃H₇O)2PS₂}3{2C₆H₅CONH₂}

Chemical Property:

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Technology Process of Gd{(C₃H₇O)2PS₂}3{2C₆H₅CONH₂}

There total 2 articles about Gd{(C₃H₇O)2PS₂}3{2C₆H₅CONH₂} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: gadolinium(III) chloride hexahydrate

: 55-21-0,27208-38-4
benzamide

: 27205-99-8
sodium O,O-diisopropyl dithiophosphate

: 93441-33-9
Gd{(C₃H₇O)2PS₂}3{2C₆H₅CONH₂}

Guidance literature:: In isopropyl alcohol; GdCl3*6H2O and (i-PrO)2PS2Na dissolved in i-PrOH, refluxed for about 20min at 80°C, filtered, less than 2 equiv. of PhCONH2 added, warmed and kept at about 65°C for 5 min; rotary evapd. at 65°C, dissolved in i-PrOH, filtered, i-Pr2O added, kept in SiO2-desiccator for several days, crystals filtered off, washed with i-PrOH and i-Pr2O, dried in vac. desiccator; elem. anal.;
DOI:10.1246/bcsj.57.2919

Reference yield:

: Gd⁽³⁺⁾*Na⁽¹⁺⁾*4(C₃H₇O)2PS₂^(1-) = Na{Gd((C₃H₇O)2PS₂)4}

: 55-21-0,27208-38-4
benzamide

: 93441-33-9
Gd{(C₃H₇O)2PS₂}3{2C₆H₅CONH₂}

Guidance literature:: In isopropyl alcohol; warming at 65°C for 5 min, evaporation at 65°C, dissolving in 2-propanol, filtration, keeping in dessicator over silicagel for several days; washing with 2-propanol and diisopropyl ether, drying in vac. desiccator;
DOI:10.1246/bcsj.57.2919