[Rh(CO)(S,N,S-HEtSNS)]OTf

Base Information

Chemical Name:[Rh(CO)(S,N,S-HEtSNS)]OTf
CAS No.:1143463-02-8
Molecular Formula:CF₃O₃S*C₃₁H₃₁N₃OP₂RhS₂
Molecular Weight:839.662
Hs Code.:

Synonyms:

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Chemical Property of [Rh(CO)(S,N,S-HEtSNS)]OTf

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Technology Process of [Rh(CO)(S,N,S-HEtSNS)]OTf

There total 1 articles about [Rh(CO)(S,N,S-HEtSNS)]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: EtNHC(S)Ph₂P=NP(+)Ph₂C(S)N(-)Et

: 1155691-04-5
Rh(CH₃CN)2(CO)2⁽¹⁺⁾*CF₃SO₃^(1-)=Rh(CH₃CN)2(CO)2CF₃SO₃

: 1143463-02-8
[Rh(CO)(S,N,S-HEtSNS)]OTf

Guidance literature:: In dichloromethane; (N2), to soln. of ligand in CH2Cl2 added soln. of 1 equiv. of Rh complexin CH2Cl2, stirred for 2 h; evapd., elem. anal.;
DOI:10.1002/ejic.200800075

Reference yield:

: 1143463-02-8
[Rh(CO)(S,N,S-HEtSNS)]OTf

: 74-88-4
methyl iodide

: 1143465-24-0
(C₂H₅NHC(S)P(C₆H₅)2NP(C₆H₅)2C(S)NC₂H₅)Rh(COCH₃)I⁽¹⁺⁾*O₃SCF₃^(1-)=[(C₂H₅NHC(S)P(C₆H₅)2NP(C₆H₅)2C(S)NC₂H₅)Rh(COCH₃)I]O₃SCF₃

Guidance literature:: In dichloromethane-d2; (N2); std. Schlenk technique; soln. of MeI in CD2Cl2 was added to soln. of Rh complex in CD2Cl2 in NMR tube at 298.16 K; NMR monitoring; Kinetics;
DOI:10.1021/om8012037

Reference yield:

: 1143463-02-8
[Rh(CO)(S,N,S-HEtSNS)]OTf

: 74-88-4
methyl iodide

: 1142818-69-6
[(C₂H₅NC(S)P(C₆H₅)2NP(C₆H₅)2C(S)NC₂H₅)Rh(COCH₃)I]

: 1143465-24-0
(C₂H₅NHC(S)P(C₆H₅)2NP(C₆H₅)2C(S)NC₂H₅)Rh(COCH₃)I⁽¹⁺⁾*O₃SCF₃^(1-)=[(C₂H₅NHC(S)P(C₆H₅)2NP(C₆H₅)2C(S)NC₂H₅)Rh(COCH₃)I]O₃SCF₃

Guidance literature:: In dichloromethane; (Ar); std. Schlenk technique; MeI (100 equiv.) was added to soln. of Rh complex (1 equiv.) in CH2Cl2 at 25°C; IR, NMR monitoring; chromd. (silica gel plate, CH2Cl2/hexane);
DOI:10.1021/om8012037