Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃OCH₃)

Base Information

• Chemical Name: Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃OCH₃)
• CAS No.: 602314-66-9
• Molecular Formula: C₅₁H₄₂N₂O₃OsP₂
• Molecular Weight: 983.054
• Mol file: 602314-66-9.mol

Synonyms:

Chemical Property of Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃OCH₃)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃OCH₃)

There total 3 articles about Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃OCH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNN6H3OCH3)]PF6 (602314-73-8) → Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNC6H3OCH3) (602314-66-9)

Guidance literature:

With Os(II)(bpy)Br₂; TBAP; In acetonitrile; addn. of Os(II)(bpy)Br2 and TBAP to acetonitrile soln. of the Os(III) complex; not isolated, detected by cyclic voltammetry;

DOI:10.1021/ic0343713

Reference yield:

Os(P(C6H5)3)2(CO)(OC6H3(CH3)NNC6H3OCH3)(1+) (602314-72-7) → Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNC6H3OCH3) (602314-66-9)

Guidance literature:

With TBAP; In dichloromethane; Electrolysis; coulometric reduction at 0.2 V in dichloromethane contg. 0.1 M TBAP;

DOI:10.1021/ic0343713

Reference yield:

Os(triphenylphosphine)2(CO)2(HCOO)2 + 2-(4'-methoxyphenylazo)-4-methylphenol (15096-05-6) → Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNC6H3OCH3) (602314-66-9)

Guidance literature:

In 2-methoxy-ethanol; addn. of Os complex to a soln. of ligand in 2-methoxyethanol (1:1 mol. ratio), heatinf at reflux for 24 h; solvent evapn. on a water bath, chromy. (TLC on a silica plate, hexane- benzene 1:1), extn. of the soln. with dichloromethane, evapn. of the extract;

DOI:10.1021/ic0343713

upstream raw materials:

Os(P(C₆H₅)3)2(CO)(OC₆H₃(CH₃)NNC₆H₃OCH₃)⁽¹⁺⁾

2-(4'-methoxyphenylazo)-4-methylphenol

[Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNN₆H₃OCH₃)]PF₆

Downstream raw materials:

[Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNN₆H₃OCH₃)]PF₆

Refernces