{(PPh3)(η-C6H6)ReH3}

Base Information

Chemical Name:{(PPh3)(η-C6H6)ReH3}
CAS No.:142196-01-8
Molecular Formula:C₂₄H₂₄PRe
Molecular Weight:529.635
Hs Code.:

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Chemical Property of {(PPh3)(η-C6H6)ReH3}

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Technology Process of {(PPh3)(η-C6H6)ReH3}

There total 5 articles about {(PPh3)(η-C6H6)ReH3} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 81368-85-6
{(PPh3)2(η-C6H8)ReH3}

: 75359-47-6
{(PPh3)2(η-C6H6)ReH}

: 142196-01-8
{(PPh3)(η-C6H6)ReH3}

Guidance literature:: In tetrahydrofuran; byproducts: P(C6H5)3; Irradiation (UV/VIS); a soln. of the dienetrihydrido-complex in THF was irradiated (medium pressure Hg lamp, Hanau 100W) at 20 °C for 30 min, evaporation of the solvent was leading to a mixture containing the mono- and di-triphenylphosphino-complex;; residue was chromd. on aluminia;;
DOI:10.1016/0022-328X(92)80072-6

Reference yield: 60.0%

: {(PPh3)2(η-C6H7)ReH2}

: 142196-01-8
{(PPh3)(η-C6H6)ReH3}

Guidance literature:: In benzene; byproducts: P(C6H5)3; Irradiation (UV/VIS); a soln. of the cyclohexadienyldihydrido-complex in benzene was irradiated (medium pressure Hg lamp, Hanau 100W) at 20 °C for 1h, evaporation of the solvent;; residue was chromd. on aluminia: PPh3 was eluted with pentane/acetone (99/1), ((PPh3)(C6H6)ReH3) with pentane/acetone (85/15), after evaporation a yellow powder was obtained, recrystn. from pentane/acetone; elem. anal.;;
DOI:10.1016/0022-328X(92)80072-6

Reference yield: 50.0%

: 12103-40-1
bis(triphenylphosphine)-rhenium heptahydride

: 558-37-2
tert-butylethylene

: 142196-01-8
{(PPh3)(η-C6H6)ReH3}

Guidance literature:: In benzene; byproducts: P(C6H5)3; Irradiation (UV/VIS); a soln. of ((PPh3)2ReH7) and 3,3-dimethylbutene in benzene was irradiated (medium pressure Hg lamp, Hanau 100W) at 20 °C for 2h, evaporation of the solvent;; residue was chromd. on aluminia: PPh3 was eluted with pentane/acetone (99/1), ((PPh3)(C6H6)ReH3) with pentane/acetone (85/15), after evaporation a yellow powder was obtained, recrystn. from pentane/acetone; elem. anal.;;
DOI:10.1016/0022-328X(92)80072-6