ReH₇*2P(C₆H₅)3=ReH₇(P(C₆H₅)3)2

Base Information

Chemical Name:ReH₇*2P(C₆H₅)3=ReH₇(P(C₆H₅)3)2
CAS No.:12103-40-1
Molecular Formula:C₃₆H₃₇P₂Re
Molecular Weight:717.844
Hs Code.:

ReH<sub>7</sub>*2P(C<sub>6</sub>H<sub>5</sub>)3=ReH<sub>7</sub>(P(C<sub>6</sub>H<sub>5</sub>)3)2

Synonyms:ReH₇*2P(C₆H₅)3=ReH₇(P(C₆H₅)3)2

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Chemical Property of ReH₇*2P(C₆H₅)3=ReH₇(P(C₆H₅)3)2

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Technology Process of ReH₇*2P(C₆H₅)3=ReH₇(P(C₆H₅)3)2

There total 5 articles about ReH₇*2P(C₆H₅)3=ReH₇(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 16853-85-3
lithium aluminium tetrahydride

: [ReOCl₃(PPh₃)₂]

: 12103-40-1
bis(triphenylphosphine)-rhenium heptahydride

Guidance literature:: In diethyl ether; under Ar; Et2O added to mixt. of Re complex and LiAlH4; stirred for 1 h; filtered; EtOH added dropwise to filtrate; evapd. to dryness; solids extd. with THF; THF ext. concd.; hexane added; ppt. filtered off, washed with hexane, dried in vac.;
DOI:10.1139/v01-071

Reference yield: 65.0%

: 16853-85-3
lithium aluminium tetrahydride

: 34248-12-9
trichlorooxobis(triphenylphosphine)rhenium(V)

: 12103-40-1
bis(triphenylphosphine)-rhenium heptahydride

Guidance literature:: In tetrahydrofuran; under N2, suspn. of Re complex in dry THF stirred at 0°C with LiAlH4 for 3 h;

Reference yield: 64.0%

: [ReOCl₃(PPh₃)₂]

: 12103-40-1
bis(triphenylphosphine)-rhenium heptahydride

Guidance literature:: With lithium aluminium hydride; In diethyl ether; ReOCl3(PPh3)2 was was placed under vac. for 1 h, ether was vac.transferred into the flask, LiAlH4 was added over 10 min, kept for 30 min; filtered, filtrate was evapd., excess LiAlH4 was decompd. by wet CH2Cl2 (-40°C) and H2O (0°C) under N2, mixt. was filtered, cooled by addn. of liq. N2, decanted, evapd. (10**-3 Torr), residue was washed with Et2O under N2, dried under vac.;