C₃₄H₃₀O₉S

Base Information

• Chemical Name: C₃₄H₃₀O₉S
• CAS No.: 1287768-50-6
• Molecular Formula: C₃₄H₃₀O₉S
• Molecular Weight: 614.673
• Mol file: 1287768-50-6.mol

Synonyms:

Chemical Property of C₃₄H₃₀O₉S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₄H₃₀O₉S

There total 6 articles about C₃₄H₃₀O₉S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucopyranoside (1287768-29-9) → C34H30O9S (1287768-50-6)

Guidance literature:

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; In dichloromethane; water; at 20 ℃;

DOI:10.1021/jo200076z

Reference yield:

phenyl 2,3-di-O-benzoyl-4,6-O-p-methoxy-benzylidene-1-thio-β-D-glucopyranoside (1287768-28-8) → C34H30O9S (1287768-50-6)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylsilane; phenylborondichloride / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere

2: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

With triethylsilane; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; phenylborondichloride; In dichloromethane; water;

DOI:10.1021/jo200076z

Reference yield:

(2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol (71676-30-7,87508-18-7,138922-03-9,87508-17-6) → C34H30O9S (1287768-50-6)

Guidance literature:

Multi-step reaction with 5 steps

1: pyridine / 0 - 20 °C

2: toluene-4-sulfonic acid / methanol; dichloromethane / 8 h / 35 °C

3: camphor-10-sulfonic acid / N,N-dimethyl-formamide / 1 h / 50 °C

4: triethylsilane; phenylborondichloride / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere

5: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

With pyridine; triethylsilane; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; camphor-10-sulfonic acid; phenylborondichloride; toluene-4-sulfonic acid; In methanol; dichloromethane; water; N,N-dimethyl-formamide;

DOI:10.1021/jo200076z

upstream raw materials:

phenyl 2,3-di-O-benzoyl-4,6-O-p-methoxy-benzylidene-1-thio-β-D-glucopyranoside

phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucopyranoside

(2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

benzoyl chloride

Downstream raw materials:

methyl 1-O-acetyl-2,3-di-O-benzoyl-4-O-p-methoxybenzyl-β-D-glucuronate

methyl 2,3-di-O-benzoyl-1-azido-β-D-glucuronate

C₅₃H₅₄N₄O₁₄

C₄₃H₄₆N₄O₁₆