rac-[2-(diphenylphosphino)ferrocenoyl]methanol

Base Information

Chemical Name:rac-[2-(diphenylphosphino)ferrocenoyl]methanol
CAS No.:494205-46-8
Molecular Formula:C₂₃H₂₁FeO₂P
Molecular Weight:416.239
Hs Code.:

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Chemical Property of rac-[2-(diphenylphosphino)ferrocenoyl]methanol

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Technology Process of rac-[2-(diphenylphosphino)ferrocenoyl]methanol

There total 3 articles about rac-[2-(diphenylphosphino)ferrocenoyl]methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 494205-48-0,173951-67-2,33056-73-4
rac-1-(diphenylphosphino)-2-(hydroxymethyl)ferrocene

: 7722-84-1
dihydrogen peroxide

: 494205-46-8,544694-51-1,494205-49-1
rac-[2-(diphenylphosphino)ferrocenoyl]methanol

Guidance literature:: In acetone; in air, 30 % aq. H2O2, stirring at 0 °C for 1 h; mixt. was diluted with H2O, ppt. was filtered off, dried in vac., dissolved in EtOAc, crystd. by hexane diffusion;
DOI:10.1039/b204655p

Reference yield: 44.0%

: rac-2-(hydroxymethyl)-1-(selanyldiphenylphosphino)-ferrocene

: 494205-46-8,544694-51-1,494205-49-1
rac-[2-(diphenylphosphino)ferrocenoyl]methanol

Guidance literature:: With 2,4-Dinitrofluorobenzene; potassium carbonate; In N,N-dimethyl-formamide; Inert atmosphere; Schlenk technique;
DOI:10.1002/ejic.201801430

Reference yield:

: 297163-59-8
(R)-3,5-dihydrodinaphtho[2,1-c:1',2'-e]selenepin 4-oxide

: 494205-48-0,173951-67-2,33056-73-4
rac-1-(diphenylphosphino)-2-(hydroxymethyl)ferrocene

: (S_p)-(2-diphenylphosphino)hydroxymethylferrocene

: 494205-49-1,494205-46-8,544694-51-1
[2-(hydroxymethyl)ferrocenyl]diphenylphosphine oxide

Guidance literature:: In dichloromethane; under N2; to soln. of selenoxide in CH2Cl2 added phosphine in CCl4, stirred at room temp. for 3 h; chromy. (SiO2), enantiomeric excess of phosphine and phosphine oxide 8% and 10% respectively; elem. anal.;
DOI:10.1246/bcsj.76.381