Allyl-pentafluorbenzolsulfenat

Base Information

• Chemical Name: Allyl-pentafluorbenzolsulfenat
• CAS No.: 81671-02-5
• Molecular Formula: C₉H₅F₅OS
• Molecular Weight: 256.196
• Mol file: 81671-02-5.mol

Synonyms:

Chemical Property of Allyl-pentafluorbenzolsulfenat

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Allyl-pentafluorbenzolsulfenat

There total 4 articles about Allyl-pentafluorbenzolsulfenat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pentafluorophenylthiol (771-62-0) → Allyl-pentafluorbenzolsulfenat (81671-02-5)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOH / adogen 64 / benzene; H₂O / phase transfer catalysis

2: m-Chloroperbenzoic acid / CH₂Cl₂ / -70 °C

With sodium hydroxide; 3-chloro-benzenecarboperoxoic acid; adogen 64; In dichloromethane; water; benzene;

DOI:10.1016/S0040-4039(01)92471-2

Reference yield:

pentafluorophenyl-prop-2-enyl thioether (70168-12-6) → Allyl-pentafluorbenzolsulfenat (81671-02-5) + Allyl-pentafluorphenylsulfoxid (81650-43-3)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -70 ℃; Title compound not separated from byproducts;

DOI:10.1016/S0040-4039(01)92471-2

Reference yield:

pentafluorobenzenesulfenyl chloride (27918-31-6) + Lithium allyl alcoholate (52203-12-0) → Allyl-pentafluorbenzolsulfenat (81671-02-5)

Guidance literature:

In Dimethyl ether; trichlorofluoromethane;

DOI:10.1021/ja00710a051

upstream raw materials:

pentafluorophenyl-prop-2-enyl thioether

pentafluorobenzenesulfenyl chloride

Lithium allyl alcoholate

Allyl-pentafluorphenylsulfoxid

Downstream raw materials:

Allyl-pentafluorphenylsulfoxid