27918-31-6

Basic information

• Product Name: PENTAFLUOROBENZENESULFENYL CHLORIDE
• Synonyms: PENTAFLUOROBENZENESULFENYL CHLORIDE;pentafluorobenzenesulphenyl chloride;PENTAFLUOROBENZENESULFENYL CHLORIDE 98%;PentafluorobenzeneSulfenic acid chloride;Pentafluorophenylsulfenyl chloride;Pentafluorobenzenesulfenyl chloride,98%
• CAS NO: 27918-31-6
• Molecular Formula: C₆ClF₅S
• Molecular Weight: 234.57
• EINECS: 248-727-4
• Mol File: 27918-31-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 210.1°Cat760mmHg
• Flash Point: 80.9°C
• Appearance: /
• Density: 1.641 (estimate)
• Vapor Pressure: 0.284mmHg at 25°C
• Refractive Index: 1.498-1.5
• CAS DataBase Reference: PENTAFLUOROBENZENESULFENYL CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PENTAFLUOROBENZENESULFENYL CHLORIDE(27918-31-6)
• EPA Substance Registry System: PENTAFLUOROBENZENESULFENYL CHLORIDE(27918-31-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26
• Hazardous Substances Data: 27918-31-6(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR ORANGE TO RED LIQUID

InChI:InChI=1/C6ClF5S/c7-13-6-4(11)2(9)1(8)3(10)5(6)12

Upstream product

• 35366-45-1 pentafluorophenylmercaptoisocyanate 
• 20364-76-5 bis(pentafluorophenylmercapto)mercury 
• 1494-06-0 bis(pentafluorophenyl) disulfide 
• 344-07-0 1-chloro-2,3,4,5,6-pentafluorobenzene 
• 12775-96-1 copper 
• 7704-34-9 sulfur 
• 771-62-0 pentafluorophenylthiol 
• 7782-50-5 chlorine 
• 21459-27-8 lead pentafluorothiophenolate 
• 13780-57-9 pentafluorosulfanyl chloride 
• 40779-99-5 Lithium; 2,3,4,5,6-pentafluoro-benzenethiolate 
• 51098-05-6 Methyl-dithiocarbamic acid pentafluorophenyl ester 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 31377-92-1 pentafluorophenylmercaptoamine 

Downstream Products

• 71855-62-4 N-(2-Propyl)-N-p-toluolsulfonyl-pentafluorobenzolsulfenylamid 
• 71855-64-6 N-(2-Methoxy-1,1-dimethyl-ethyl)-4-methyl-N-pentafluorophenylsulfanyl-benzenesulfonamide 
• 71855-66-8 N-(1-Phenethyl)-N-p-toluolsulfonyl-pentafluorbenzolsulfenylamid 
• 73162-49-9 Acetic acid 1-pentafluorophenylsulfanylmethyl-allyl ester 
• 73162-55-7 Acetic acid 1-methyl-1-pentafluorophenylsulfanylmethyl-allyl ester 
• 542-18-7 cyclohexyl chloride 
• 56717-64-7 pentafluorophenyl-cyclohexyl thioether 
• 14999-80-5 trifluoromethyl pentafluorophenyl disulfide 
• 1494-06-0 bis(pentafluorophenyl) disulfide 
• 33288-16-3 benzyl pentafluorophenyl sulfide 
• 100-44-7 benzyl chloride 
• 147150-97-8 Bis(pentafluorphenylsulfanyl)keten 
• 156664-28-7 1,1,1-Triethoxy-2-(pentafluorphenylsulfanyl)ethan 
• 156664-29-8 1,1,1-Triethoxy-2,2-bis(pentafluorphenylsulfanyl)ethan 

Relevant articles and documents

Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5

Replacement of the thiol group in polyfluoroarenethiols with chlorine was performed by treating with PCl5 as chlorinating agent. By heating in ampules at 200-220°C polyfluoro- and polyfluorochloroarenethiols with PCl5 mono- and dichloropolyfluoroarenes and also 1,2,4-trifluorotrichlorobenzene were synthesized. Dichloropolyfluoroarenes contain chlorine atoms in ortho- and para-positions.

THIOL-PROTECTED AMINO ACID DERIVATIVES AND USES THEREOF

The present invention relates to thiol-protected amino acid derivatives of formulae (I) and (II), peptides and block-copolymers containing the compounds and methods for preparing same. The present invention also relates to core-shell particles comprising such thiol-protected block-copolymers and compositions thereof.

Organofluorine sulfur-containing compounds: V. Joint pyrolysis with chlorine or bromine of polyfluoroarenethioles, polyfluorohetarenethioles, and their derivatives

Joint pyrolysis with chlorine and bromine of polyfluoroarenethiols, -hetarenethiols, and their derivatives at 300-650°C furnished polyfluorocompounds containing chlorine and bromine. 2005 Pleiades Publishing, Inc.