Ph₄As[Ir(CO)₂Cl₂]

Base Information

Chemical Name:Ph₄As[Ir(CO)₂Cl₂]
CAS No.:15152-88-2
Molecular Formula:C₂Cl₂IrO₂*C₂₄H₂₀As
Molecular Weight:702.491
Hs Code.:

Ph<sub>4</sub>As[Ir(CO)<sub>2</sub>Cl<sub>2</sub>]

Synonyms:

Suppliers and Price of Ph₄As[Ir(CO)₂Cl₂]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ph₄As[Ir(CO)₂Cl₂]

Chemical Property:

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Technology Process of Ph₄As[Ir(CO)₂Cl₂]

There total 1 articles about Ph₄As[Ir(CO)₂Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: iridium(III) chloride trihydrate

: 507-28-8,14842-08-1
tetraphenylarsonium chloride

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 15152-88-2,29629-78-5
Ph₄As[Ir(CO)₂Cl₂]

Guidance literature:: In N,N-dimethyl-formamide; reagents except for Ph4AsCl mixed in DMF, soln. heated under reflux for 50 min., HCl added, refluxed for 10 min, cooled to room temp., Ph4AsCl added; solvent evapd., washed with acetone/diethyl ether (1:9), elem. anal.;
DOI:10.1002/1099-0682(200109)2001:9<2327::AID-EJIC2327>3.0.CO;2-D

Reference yield: 92.0%

: 15152-88-2,29629-78-5
Ph₄As[Ir(CO)₂Cl₂]

: 23176-19-4
(diphenylphosphinomethyl)diphenylphosphine selenide

: Ir(CO)Cl(PPh₂CH₂P(Se)Ph₂)₂

: 507-28-8,14842-08-1
tetraphenylarsonium chloride

Guidance literature:: In dichloromethane; at 20 ℃; for 0.005h;
DOI:10.1016/j.poly.2020.114344

Reference yield:

: 15152-88-2,29629-78-5
Ph₄As[Ir(CO)₂Cl₂]

: 28225-52-7
8-(diphenylphosphino)quinoline

: 82704-74-3
chlorocarbonyl 8-(diphenylphosphino)quinoline iridium(I)

Guidance literature:: In ethanol; dichloromethane; to a soln. of the Ir complex in 2-methoxyethanol was added a soln. of ligand in EtOH/CH2Cl2; mixt. stirred in an ice-bath for 2 h; the solid was filtered, washed with EtOH and ether; elem. anal.;
DOI:10.1016/S0020-1693(00)91178-2