t-butyldimesitylsilane

Base Information

• Chemical Name: t-butyldimesitylsilane
• CAS No.: 119106-08-0
• Molecular Formula: C₂₂H₃₂Si
• Molecular Weight: 324.582
• Mol file: 119106-08-0.mol

Synonyms:

Chemical Property of t-butyldimesitylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of t-butyldimesitylsilane

There total 5 articles about t-butyldimesitylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

chloro-di-(2,4,6-trimethylphenyl)silane (50490-74-9) + tert.-butyl lithium (594-19-4) → t-butyldimesitylsilane (119106-08-0)

Guidance literature:

In hexane; for 2h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/om400366z

Reference yield: 88.0%

tert.-butyl lithium (594-19-4) + dimesitylfluorosilane (119106-07-9) → t-butyldimesitylsilane (119106-08-0)

Guidance literature:

In pentane; for 18h; Heating;

DOI:10.1016/0022-328X(88)89074-0

Reference yield:

2,4,6-trimethylphenyl bromide (576-83-0) → t-butyldimesitylsilane (119106-08-0)

Guidance literature:

Multi-step reaction with 4 steps

1: n-BuLi / hexane / 8 h

2: 74 percent / trichlorosilane / benzene

3: 80 percent / KF / acetonitrile

4: 88 percent / pentane / 18 h / Heating

With potassium fluoride; n-butyllithium; trichlorosilane; In hexane; acetonitrile; pentane; benzene;

DOI:10.1016/0022-328X(88)89074-0

upstream raw materials:

tert.-butyl lithium

dimesitylfluorosilane

2,4,6-trimethylphenyl bromide

chloro-di-(2,4,6-trimethylphenyl)silane

Downstream raw materials:

1,1-dimethyl-2,2-dimesityl-2-t-butyldisilane

1-tert-Butyl-2-chloro-2,2-dimethyl-1,1-bis-(2,4,6-trimethyl-phenyl)-disilane

1-tert-Butyl-2,2-diisopropyl-1,1-bis-(2,4,6-trimethyl-phenyl)-disilane

1-tert-Butyl-2-chloro-2,2-diisopropyl-1,1-bis-(2,4,6-trimethyl-phenyl)-disilane