Cp2ZrH((μ-H)2BHPh)

Base Information

Chemical Name:Cp2ZrH((μ-H)2BHPh)
CAS No.:847056-82-0
Molecular Formula:C₁₆H₁₉BZr
Molecular Weight:313.362
Hs Code.:

Synonyms:

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Chemical Property of Cp2ZrH((μ-H)2BHPh)

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Technology Process of Cp2ZrH((μ-H)2BHPh)

There total 2 articles about Cp2ZrH((μ-H)2BHPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.6%

: Cp2ZrCl((μ-H)2BHPh)2*0.5toluene

: 121-44-8
triethylamine

: 847056-82-0
Cp2ZrH((μ-H)2BHPh)

: 857404-98-9
phenylborane; compound with triethylamine (1:1)

Guidance literature:: In toluene; (drybox); addn. of toluene to zirconium complex at -78°C, addn. of amine, warming to room temp., stirring for 4 h; evapn., dissolving in Et2O, storage at -35°C, manual sepn.;
DOI:10.1016/j.jorganchem.2004.09.026

Reference yield: 9.6%

: Schwartz's reagent

: lithium (trihydro)phenylborate

: 847056-82-0
Cp2ZrH((μ-H)2BHPh)

Guidance literature:: In toluene; (drybox); addn. of toluene to a mixt. of zirconium complex and lithium salt at -78°C, warming to room temp., stirring overnight; filtration, evapn., standing at room temp.; elem. anal.;
DOI:10.1016/j.jorganchem.2004.09.026

Reference yield: 66.0%

: 60-29-7,927820-24-4
diethyl ether

: 847056-82-0
Cp2ZrH((μ-H)2BHPh)

: 1109-15-5
tris(pentafluorophenyl)borate

: 941578-51-4
[Cp2Zr(OEt2)((μ-H)2BHPh)][HB(C6F5)3]

Guidance literature:: In diethyl ether; under N2 atm. to Zr complex and B(C6F5)3 Et2O was added at -78°C,allowed to warm to room temp. and stirred for 4 h; solvent was removed, residue was dissolved in Et2O and layered with hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2007.02.031