Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-)

Base Information

Chemical Name:Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-)
CAS No.:122068-60-4
Molecular Formula:BF₄*C₄₄H₄₁FMoP₃
Molecular Weight:864.474
Hs Code.:

Synonyms:

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Chemical Property of Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-)

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Technology Process of Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-)

There total 3 articles about Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: tetrafluoroboric acid

: 98703-44-7
Mo(η6-PhPPh2)(dppe)(PPh3)

: 122068-60-4
Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-)

: Mo(η6-C6H6)(dppe)(PPh2OH)(H)(1+)*BF4(1-)

Guidance literature:: In water; benzene; byproducts: {Mo(O)(F)(dppe)2}(1+), {PPh3CMe2CH2COMe}(1+), HPPh3(1+); dropwise addn. of aq. HBF4 to a soln. of the complex in water-satd. benzene (room temp.), formation of a brown oil (after 5 min) and a colorless benzene supernatant (after 10 min), removing of benzene and water; further product: PPh3; dry-pumping of the residue, redissolving in THF, chromy. (Al2O3);

Reference yield:

: 98703-44-7
Mo(η6-PhPPh2)(dppe)(PPh3)

: 7664-39-3,12381-92-9,32057-09-3,74835-82-8
hydrogen fluoride

: 122068-60-4
Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-)

: Mo(η6-C6H6)(dppe)(PPh2OH)(H)(1+)*BF4(1-)

Guidance literature:: In benzene; vigorous stirring of the soln. of the complex in benzene, introducing of HF gas above the soln., instantaneous formation of a brown oil, stopping of the HF flow, purging the flask vigorously with Ar, cooling, syringing of the supernatant, neutralizing; dissolving in acetone; detn. by 31P-NMR;

Reference yield:

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 98703-44-7
Mo(η6-PhPPh2)(dppe)(PPh3)

: 122068-60-4
Mo(η6-C6H6)(dppe)(PPh2F)(H)(1+)*BF4(1-)

: Mo(η6-C6H6)(dppe)(PPh2OH)(H)(1+)*BF4(1-)

Guidance literature:: In benzene; byproducts: HPPh3(1+); dropwise addn. of HBF4*Et2O at room temp. to the complex in dry benzene under Ar to a brown soln. (stirring), immediate formation of a brown oily ppt., decanting of the colorless supernatant, pumping of the residue to dryness; dissolving in THF, chromy. (alumina) to a red-orange soln., isolation by addn. of Et2O and cooling to -40°C;